Solubility and Metastable Zone Width of Sodium Tetraborate Decahydrate in a Solution Containing Lithium Chloride

被引：10
|
作者：
Peng, Jiaoyu [1 ]
Nie, Zhen [3 ]
Li, Lili [1 ,2 ]
Wang, Liping [1 ,2 ]
Dong, Yaping [1 ]
Li, Wu [1 ]
机构：
[1] Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
[3] Chinese Acad Geol Sci, Beijing 100037, Peoples R China
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2013年 / 58卷 / 05期
基金：
中国国家自然科学基金;
关键词：
SALT LAKE; IMPURITIES; AMMONIUM; CRYSTALLIZATION; ADDITIVES; GROWTH; BORAX; IONS;
D O I：
10.1021/je400070j
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The solubility and the metastable zone width of sodium tetraborate decahydrate in solutions containing lithium chloride have been measured at temperature a range of (20 to 35) degrees C. It is found that the lithium impurity has a salt-in effect on the solubility of sodium tetraborate decahydrate. The metastable zone width broadens with an increase of the impurity concentrations. This increase can be attributed to the absorption mechanism on the crystal surface. The apparent nucleation order of sodium tetraborate decahydrate with and without impurity was calculated by a modified regression method. The results show that the addition of lithium impurity has no great effect on the apparent nucleation order of sodium tetraborate decahydrate.
引用
收藏
页码：1288 / 1293
页数：6
相关论文
共 50 条
  • [41] On the linear and integral models for metastable zone width determined by solution cooling method
    Sangwal, Keshra
    [J]. JOURNAL OF CRYSTAL GROWTH, 2021, 576
  • [42] A contemporary method to enhance the metastable zone width for crystal growth from solution
    Srinivasan, K
    Meera, K
    Ramasamy, P
    [J]. MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2001, 84 (03): : 233 - 236
  • [43] Computer simulation of metastable zone width for unseeded potassium sulfate aqueous solution
    Kobari, M.
    Kubota, N.
    Hirasawa, I.
    [J]. JOURNAL OF CRYSTAL GROWTH, 2011, 317 (01) : 64 - 69
  • [44] Introducing a Fast Method to Determine the Solubility and Metastable Zone Width for Proteins: Case Study Lysozyme
    Maosoongnern, Somchai
    Borbon, Viviana Diaz
    Flood, Adrian E.
    Ulrich, Joachim
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (46) : 15251 - 15257
  • [45] Spectrophotometry as a Method for the Determination of Solubility of Sucrose in Water and Metastable Zone Width of its Aqueous Solutions
    Borji, Abdelali
    Jourani, Abdelaziz
    [J]. CRYSTAL RESEARCH AND TECHNOLOGY, 2018, 53 (06)
  • [46] Thermodynamic modeling of gas solubility in aqueous sodium chloride solution
    Sun, Li
    Liang, Jierong
    [J]. CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2021, 38 : 184 - 195
  • [47] Thermodynamic modeling of gas solubility in aqueous sodium chloride solution
    Li Sun
    Jierong Liang
    [J]. Chinese Journal of Chemical Engineering, 2021, 38 (10) : 184 - 195
  • [48] Determination of metastable zone width, induction time and primary nucleation kinetics for cooling crystallization of sodium orthovanadate from NaOH solution
    Wang, Shaona
    Feng, Man
    Du, Hao
    Weigand, Jan J.
    Zhang, Yi
    Wang, Xindong
    [J]. JOURNAL OF CRYSTAL GROWTH, 2020, 545
  • [49] Simulation of metastable zone width and induction time for a seeded aqueous solution of potassium sulfate
    Kobari, M.
    Kubota, N.
    Hirasawa, I.
    [J]. JOURNAL OF CRYSTAL GROWTH, 2010, 312 (19) : 2734 - 2739
  • [50] Determination of metastable zone width of potassium sulfate in aqueous solution by ultrasonic sensor and FBRM
    Luo, Mengjie
    Liu, Chenglin
    Xue, Jin
    Li, Ping
    Yu, Jianguo
    [J]. JOURNAL OF CRYSTAL GROWTH, 2017, 469 : 144 - 153
12345