Solubility and Metastable Zone Width of Sodium Tetraborate Decahydrate in a Solution Containing Lithium Chloride

被引：10
|
作者：
Peng, Jiaoyu [1 ]
Nie, Zhen [3 ]
Li, Lili [1 ,2 ]
Wang, Liping [1 ,2 ]
Dong, Yaping [1 ]
Li, Wu [1 ]
机构：
[1] Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
[3] Chinese Acad Geol Sci, Beijing 100037, Peoples R China
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2013年 / 58卷 / 05期
基金：
中国国家自然科学基金;
关键词：
SALT LAKE; IMPURITIES; AMMONIUM; CRYSTALLIZATION; ADDITIVES; GROWTH; BORAX; IONS;
D O I：
10.1021/je400070j
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The solubility and the metastable zone width of sodium tetraborate decahydrate in solutions containing lithium chloride have been measured at temperature a range of (20 to 35) degrees C. It is found that the lithium impurity has a salt-in effect on the solubility of sodium tetraborate decahydrate. The metastable zone width broadens with an increase of the impurity concentrations. This increase can be attributed to the absorption mechanism on the crystal surface. The apparent nucleation order of sodium tetraborate decahydrate with and without impurity was calculated by a modified regression method. The results show that the addition of lithium impurity has no great effect on the apparent nucleation order of sodium tetraborate decahydrate.
引用
收藏
页码：1288 / 1293
页数：6
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