Toward Water-Based Recycling Techniques: Methodologies for Homogeneous Catalyst Recycling in Liquid/Liquid Multiphase Media and Their Implementation in Continuous Processes

被引：26

作者：

Roesler, T. ^{[1
]}

Fassbach, T. A. ^{[1
]}

Schrimpf, M. ^{[1
]}

Vorholt, A. J. ^{[1
]}

Leitner, W. ^{[1
]}

机构：

[1] Max Planck Inst Chem Energy Convers, Stiftstr 34, D-45470 Mulheim, Germany

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2019年 / 58卷 / 07期

关键词：

LEAN AQUEOUS HYDROFORMYLATION; RHODIUM-BIPHEPHOS CATALYST; BIPHASIC HYDROFORMYLATION; OLEFIN METATHESIS; BETA-CYCLODEXTRIN; HYDROGEN-PEROXIDE; REACTION NETWORK; PROCESS DESIGN; METHYL OLEATE; SOLVENT;

D O I：

10.1021/acs.iecr.8b04295

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Biphasic water-based solvent systems offer the opportunity of efficient recycling of homogeneous catalysts. Water separates well from most organic solvents; therefore, water-soluble catalysts can be immobilized in this phase. Furthermore, water can substitute hazardous and environmentally unfriendly organic solvents in these systems. Within industry only the Ruhrchemie/Rhosne-Poulenc process uses plain water to immobilize the homogeneous catalyst for the hydroformylation of propene. Yet for more hydrophobic substrates, no water-based system has been commercialized. This review will summarize recent developments in the field of water-based recycling strategies. Topics in this field are the intensification of the mixing process, the use of thermomorphic solvent systems, and the employment of several additives, like alcohols and surfactants. Continuously operated processes for these recycling strategies will be presented and discussed.

引用

页码：2421 / 2436

页数：16

共 26 条

[21] Sequential fractionation of sugarcane bagasse using liquid hot water and formic acid-catalyzed glycerol-based organosolv with solvent recycling
Chayanon Chotirotsukon
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[J]. BioEnergy Research, 2021, 14 : 135 - 152
[22] Solid-phase extraction coupled with switchable hydrophilicity solvent-based homogeneous liquid–liquid microextraction for chloramphenicol enrichment in environmental water samples: a novel alternative to classical extraction techniques
Xin Di
Xin Wang
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Xin Di
[J]. Analytical and Bioanalytical Chemistry, 2019, 411 : 803 - 812
[23] Solid-phase extraction coupled with switchable hydrophilicity solvent-based homogeneous liquid-liquid microextraction for chloramphenicol enrichment in environmental water samples: a novel alternative to classical extraction techniques
Di, Xin
Wang, Xin
Liu, Youping
Guo, Xingjie
Di, Xin
[J]. ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2019, 411 (04) : 803 - 812
[24] Separation of Rare Earths from the Transition Metals Using a Novel Ionic-Liquid-Based Aqueous Two-Phase System: Toward Green and Efficient Recycling of Rare Earths from the NdFeB Magnets
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Huang, Kun
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[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2018, 57 (49) : 16934 - 16943
[25] Liquid-Phase Oxidation of Inorganic Sulfides in Aqueous Media in the Presence of a Homogeneous Catalyst Based on 3,3′,5,5′-Tetra-tert-Butyl-4,4′-Stilbenequinone
Hoang, H. Y.
Akhmadullin, R. M.
Akhmadullina, F. Yu.
Zakirov, R. K.
Akhmadullina, A. G.
[J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2018, 63 (02) : 256 - 261
[26] Liquid-Phase Oxidation of Inorganic Sulfides in Aqueous Media in the Presence of a Homogeneous Catalyst Based on 3,3′,5,5′-Tetra-tert-Butyl-4,4′-Stilbenequinone
H. Y. Hoang
R. M. Akhmadullin
F. Yu. Akhmadullina
R. K. Zakirov
A. G. Akhmadullina
[J]. Russian Journal of Inorganic Chemistry, 2018, 63 : 256 - 261

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