Effect of intramolecular hydrogen bonding on biomimetic reactions by flavins

被引：1
|
作者：
Geetanjali [1 ]
Singh, Ram [2 ]
机构：
[1] Univ Delhi, Dept Chem, Kirori Mal Coll, Delhi 110007, India
[2] Delhi Technol Univ, Dept Appl Chem & Polymer Technol, Delhi, India
来源：
HETEROCYCLIC COMMUNICATIONS | 2013年 / 19卷 / 04期
关键词：
biomimetic reactions; flavin; hydrogen bonding; thioanisole; 10-SUBSTITUTED ISOALLOXAZINES; SOLID ACIDS; 4A-HYDROPEROXYFLAVIN; CATALYSIS; OXIDATION; AMINES; OXYGEN;
D O I：
10.1515/hc-2013-0022
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Selected 6- and 7-carboxyflavins activate H2O2, oxidizing thioanisole to its sulfoxide. The greater reactivity of the 6-carboxyflavin derivatives are ascribed to the intramolecular hydrogen bonding between N(5) and the carboxyl group of the flavin system.
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页码：261 / 263
页数：3
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