Dinitrogen Fixation Activated by Binuclear Transition-Metal Complexes

被引：0

作者：

Ma Xuelu ^{[1
]}

Lei Ming ^{[1
]}

机构：

[1] Beijing Univ Chem Technol, Coll Sci, Inst Mat Med, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China

来源：

PROGRESS IN CHEMISTRY | 2013年 / 25卷 / 08期

关键词：

transition-metal complexes; nitrogen fixation; dinitrogen cleavage; functionalization; CO/CO2 induced dinitrogen activation; ON-BOUND DINITROGEN; BRIDGING N-2 UNIT; C BOND FORMATION; SIDE-ON; END-ON; COORDINATED DINITROGEN; MOLYBDENUM COMPLEXES; VANADIUM COMPLEXES; TANTALUM COMPLEX; CLEAVAGE;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dinitrogen fixation activated by organometallic complexes under mild conditions is one of hot fields in modern industry, which try to convert abound but quite inert dinitrogen into ammonia or other nitrogenous compounds. In this review, coordination modes of N-2 molecule with transition-metal complexes are classified, and the main factors such as steric effect and electronic effect on the dinitrogen activation and functionalization promoted by dinuclear transition-metal complexes are surveyed. This review attempts to summarize recent experimental and theoretical studies concerning the reactivity patterns of dinitrogen with binuclear transition-metal complexes in the dinitrogen cleavage and functionalization as well as the CO/CO2 induced N-2 activation. The prospects of dinitrogen fixation activated by transition-metal complexes is presented, which is hoped to assist chemists in guiding research in the future.

引用

页码：1325 / 1333

页数：9

共 48 条

[41] Di- and Tetrametallic Hafnocene Oxamidides Prepared from CO-Induced N2 Bond Cleavage and Thermal Rearrangement to Hafnocene Cyanide Derivatives
Semproni, Scott P.
Margulieux, Grant W.
Chirik, Paul J.
[J]. ORGANOMETALLICS, 2012, 31 (17) : 6278 - 6287
[42] Synthesis of [(HIPTNCH2CH2)3N]V compounds (HIPT=3,5-(2,4,6-i-Pr3C6H2)2C6H3) and an evaluation of vanadium for the reduction of dinitrogen to ammonia
Smythe, Nathan C.
Schrock, Richard R.
Mueller, Peter
Weare, Walter W.
[J]. INORGANIC CHEMISTRY, 2006, 45 (23) : 9197 - 9205
[43] Studt F, 2006, DALTON T, P1137, DOI 10.1039/b514879k
[44] Side-on bridging coordination of N2:: Spectroscopic characterization of the planar Zr2N2 core and theoretical investigation of its butterfly distortion
Studt, F
Morello, L
Lehnert, N
Fryzuk, MD
Tuczek, F
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (02) : 520 - 530
[45] On the unprecedented level of dinitrogen activation in the calix[4]arene complex of Nb(III)
Terrett, R.
Cavigliasso, G.
Stranger, R.
Yates, B. F.
[J]. DALTON TRANSACTIONS, 2011, 40 (42) : 11267 - 11275
[46] Wolf J M, 1996, ORGANOMETALLICS, V15, P4977
[47] Reaction of H2 with a binuclear zirconium dinitrogen complex -: Evaluation of theoretical models and hybrid approaches
Yates, Brian F.
Basch, Harold
Musaev, Djamaladdin G.
Morokuma, Keiji
[J]. JOURNAL OF CHEMICAL THEORY AND COMPUTATION, 2006, 2 (05) : 1298 - 1316
[48] Ditantalum Dinitrogen Complex: Reaction of H2 Molecule with "End-on-Bridged" [TaIV]2(μ-η1:η1-N2) and Bis(μ-nitrido) [TaV]2(μ-N)2 Complexes
Zhang, Wenchao
Tang, Yanhui
Lei, Ming
Morokuma, Keiji
Musaev, Djamaladdin G.
[J]. INORGANIC CHEMISTRY, 2011, 50 (19) : 9481 - 9490

← 1 2 3 4 5 →