Aryl Ketones as Single-Electron-Transfer Photoredox Catalysts in the Nickel-Catalyzed Homocoupling of Aryl Halides

被引：33
|
作者：
Masuda, Yusuke [1 ]
Ishida, Naoki [1 ]
Murakami, Masahiro [1 ]
机构：
[1] Kyoto Univ, Dept Synthet Chem & Biol Chem, Kyoto 6158510, Japan
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 2016卷 / 35期
基金：
日本科学技术振兴机构; 日本学术振兴会;
关键词：
Photoredox catalysis; Nickel; C-C coupling; Homogeneous catalysis; Biaryls; VISIBLE-LIGHT PHOTOCATALYSIS; METAL-FREE; DUAL CATALYSIS; MERGING PHOTOREDOX; C(SP(3))-H BONDS; POLYMERIZATION; MECHANISM; COMPLEXES; RADICALS; AMINES;
D O I：
10.1002/ejoc.201601352
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An intriguing photoredox system for the homocoupling of aryl halides is reported wherein thioxanthone catalyzes a single-electron transfer from an amine reductant to nickel.
引用
收藏
页码：5822 / 5825
页数：4
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