Novel, well-defined polystyrene with a fluorine cluster end-capped group: Synthesis, characterization, and surface properties

被引：18
|
作者：
Li, Hong
Zhang, Yong Ming [1 ]
Zhang, Heng
Xue, Min Zhao
Liu, Yan Gang
机构：
[1] Shanghai Jiao Tong Univ, Coll Chem & Chem Engn, Shanghai 200240, Peoples R China
[2] Dongyue Polymer Co, Shandong, Peoples R China
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2006年 / 44卷 / 12期
关键词：
controlled radical polymerization (CRP); fluorinated polystyrene; surface modification; surface properties; surface; modification;
D O I：
10.1002/pola.21486
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Novel, well-defined fluorinated polystyrene was synthesized for the first time via the controlled radical polymerization of styrene through a relatively simple process and was characterized with H-1 NMR, F-19 NMR, and gel permeation chromatography. The surface properties of polystyrene and poly(acrylonitrile-co-butadiene-co-styrene) films were modified with the obtained polymers. X-ray photoelectron spectroscopy measurements of the air-side surface composition of the modified poly(acrylonitrile-co-butadiene-co-styrene) films showed that fluorine enriched the outermost surface, resulting in fantastic surface properties that came close to those of poly(tetrafluoroethylene). (c) 2006 Wiley Periodicals, Inc.
引用
收藏
页码：3853 / 3858
页数：6
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