Direct generation of hydrogen peroxide from formic acid and O2 using heterogeneous Pd/γ-Al2O3 catalysts

被引：32

作者：

Yalfani, Mohammad S. ^{[1
]}

Contreras, Sandra ^{[1
]}

Medina, Francesc ^{[1
]}

Sueiras, Jesus ^{[1
]}

机构：

[1] Univ Rovira & Virgili, Dept Engn Quim, Tarragona 43007, Spain

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 33期

关键词：

D O I：

10.1039/b803149e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogen peroxide formation is achieved with remarkable productivity at ambient conditions (25 degrees C and atmospheric pressure) in aqueous medium using a heterogeneous catalytic system; formic acid is decomposed in the presence of a continuous flow of O(2) over Pd/gamma-Al(2)O(3) catalyst leading to the generation of hydrogen peroxide; the addition of a negligible amount of bromide ion improves the selectivity of the reaction.

引用

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页码：3885 / 3887

页数：3

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