Carbonyl(diphenylcyclopentadienyl)- and carbonyl(tetraphenylcyclopentadienyl)rhodium(I) complexes

被引：2
|
作者：
Schumann, H [1 ]
Stenz, S [1 ]
机构：
[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2001年 / 56卷 / 12期
关键词：
(diphenylcyclopentadienyl)rhodium complexes; (tetraphenylcyclopentadienyl)rhodium complexes;
D O I：
10.1515/znb-2001-1207
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
[Rh(CO)(2)Cl](2) reacts with 1,3-diphenylcyclopentadienyl sodium or tetraphenylcyclopentadienyl sodium with formation of (1,3-Ph2C5H3)Rh(CO)(2) (1) or (C5HPh4)Rh(CO)(2) (2), respectively. The reaction of 1 or 2 with PPh3 yields the corresponding carbonyl-(cyclopentadienyl)(triphenylphosphane)rhodium complexes (1,3-Ph2C5H3)Rh(CO)(PPh3) (3) or (C5HPh4)Rh(CO)(PPh3) (4). The H-1 and C-13 NMR spectra of the new compounds are reported and discussed.
引用
收藏
页码：1293 / 1296
页数：4
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