Carbonyl(diphenylcyclopentadienyl)- and carbonyl(tetraphenylcyclopentadienyl)rhodium(I) complexes

被引：2

作者：

Schumann, H ^{[1
]}

Stenz, S ^{[1
]}

机构：

[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2001年 / 56卷 / 12期

关键词：

(diphenylcyclopentadienyl)rhodium complexes; (tetraphenylcyclopentadienyl)rhodium complexes;

D O I：

10.1515/znb-2001-1207

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Rh(CO)(2)Cl](2) reacts with 1,3-diphenylcyclopentadienyl sodium or tetraphenylcyclopentadienyl sodium with formation of (1,3-Ph2C5H3)Rh(CO)(2) (1) or (C5HPh4)Rh(CO)(2) (2), respectively. The reaction of 1 or 2 with PPh3 yields the corresponding carbonyl-(cyclopentadienyl)(triphenylphosphane)rhodium complexes (1,3-Ph2C5H3)Rh(CO)(PPh3) (3) or (C5HPh4)Rh(CO)(PPh3) (4). The H-1 and C-13 NMR spectra of the new compounds are reported and discussed.

引用

页码：1293 / 1296

页数：4

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