Convenient and improved protocols for the hydrogenation of esters using Ru catalysts derived from (P,P), (P,N,N) and (P,N,O) ligands

被引：38

作者：

Carpenter, Ian ^{[1
]}

Eckelmann, Susan C. ^{[2
]}

Kuntz, Michael T. ^{[2
]}

Fuentes, Jose A. ^{[1
]}

France, Marcia B. ^{[2
]}

Clarke, Matthew L. ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, EaStCHEM, St Andrews, Fife, Scotland

[2] Washington & Lee Univ, Dept Chem, Lexington, VA 24450 USA

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 34期

基金：

英国工程与自然科学研究理事会;

关键词：

ASYMMETRIC HYDROGENATION; RUTHENIUM COMPLEX; REDUCTION; ALCOHOLS; KETONES; ENANTIOSELECTIVITY;

D O I：

10.1039/c2dt30973d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An improved protocol where a pre-cursor, [Ru(Cl)(2)(NBD)-(Py)(2)], is treated with ligands to form [RuCl2(bidentate ligand)(diamine)] pre-catalysts for ester hydrogenation is reported. This family of catalysts, as well as a range of ruthenium complexes of tridentate P boolean AND N boolean AND X (X = NR2, OH) ligands have been investigated in the hydrogenation of aromatic esters. A range of aromatic esters can be hydrogenated in high yields at temperatures between 30 degrees C and 100 degrees C.

引用

页码：10136 / 10140

页数：5

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