Steam deactivation of transition metal MFI zeolite catalysts for NOx reduction

被引:0
|
作者
Budi, P [1 ]
CurryHyde, E [1 ]
Howe, RF [1 ]
机构
[1] UNIV NEW S WALES, DEPT CHEM ENGN, SYDNEY, NSW 2052, AUSTRALIA
关键词
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中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effects of hydrothermal treatment on the performance of Cu, Co, and Mn exchanged MFI zeolite catalysts for the selective reduction of NO with hydrocarbons has been investigated. It is shown that the deterioration of catalyst activity on exposure to steam is due to dealumination of the zeolite framework, causing loss of cation exchange capacity and residual Bronsted acidity, and in the case of Cu resultant aggregation of the transition metal component on the external surface of the zeolite.
引用
收藏
页码:1549 / 1556
页数:8
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