Synthesis of tangutorine

被引：16
|
作者：
Ho, TL [1 ]
Chen, CK [1 ]
机构：
[1] Natl Chiao Tung Univ, Dept Appl Chem, Hsinchu 30050, Taiwan
来源：
HELVETICA CHIMICA ACTA | 2006年 / 89卷 / 01期
关键词：
D O I：
10.1002/hlca.200690003
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Tangutorine (1) in the racemic form has been assembled from tryptamine and aldehyde 3. The synthetic design was based on uncovering a hidden symmetry in the nontryptamine portion of the norketone 2. A five-step process with an overall yield of 7% was developed in which 2 was transformed into the target molecule via a Vilsineier-Haack reaction and two reduction steps.
引用
收藏
页码：122 / 126
页数：5
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