Synthesis of dimethyl carbonate from propylene carbonate and methanol using CaO-ZrO2 solid solutions as highly stable catalysts

被引：75
|
作者：
Wang, Hui
Wang, Mouhua
Zhang, Wenyu
Zhao, Ning
Wei, Wei
Sun, Yuhan [1 ]
机构：
[1] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
来源：
CATALYSIS TODAY | 2006年 / 115卷 / 1-4期
关键词：
dimethyl carbonate; transesterification; CaO-ZrO2; solid solution;
D O I：
10.1016/j.cattod.2006.02.031
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
CaO-ZrO2 catalysts were prepared by coprecipitation and their catalytic performances were evaluated in the synthesis of dimethyl carbonate from propylene carbonate and methanol. The characterization by XRD, N-2 adsorption, XPS and CO2-TPD indicated that Ca2+ ion substituted for Zr4+ ions in the host lattice to form homogeneous CaO-ZrO2 solid solution when Ca/(Ca + Zr) ratio changed from 0.1 to 0.3, and CaO segregated at grain boundaries with Ca/(Ca + Zr) ratio from 0.4 to 0.5. As a result, the catalysts showed different activity and stability towards the transesterification of propylene carbonate and methanol into dimethyl carbonate. The activity of catalysts was improved with increase in Ca content. whereas high stability was shown with Ca/(Ca + Zr) ratio below 0.3. The formation of homogeneous CaO-ZrO2 solid solution was responsible for the stability of catalysts. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：107 / 110
页数：4
相关论文
共 50 条
  • [31] On the deactivation of alkali solid catalysts for the synthesis of glycerol carbonate from glycerol and dimethyl carbonate
    Jiabo Li
    Tao Wang
    Reaction Kinetics, Mechanisms and Catalysis, 2011, 102 : 113 - 126
  • [32] On the deactivation of alkali solid catalysts for the synthesis of glycerol carbonate from glycerol and dimethyl carbonate
    Li, Jiabo
    Wang, Tao
    REACTION KINETICS MECHANISMS AND CATALYSIS, 2011, 102 (01) : 113 - 126
  • [33] Synthesis of Dimethyl Carbonate from Propylene Carbonate and Methanol Over Y2O3/CeO2-La2O3 Catalysts
    Song, Ji Hwan
    Jun, Jin Oh
    Kang, Ki Hyuk
    Han, Seung Ju
    Yoo, Jaekyeong
    Park, Seungwon
    Kim, Do Heui
    Song, In Kyu
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2016, 16 (10) : 10810 - 10815
  • [34] Synthesis of dimethyl carbonate from ethylene carbonate and methanol using TS-1 as solid base catalyst
    Tatsumi, T
    Watanabe, Y
    Koyano, KA
    CHEMICAL COMMUNICATIONS, 1996, (19) : 2281 - 2282
  • [35] Synthesis of MDI from dimethyl carbonate over solid catalysts
    Zhao, XQ
    Wang, YJ
    Wang, SF
    Yang, HJ
    Zhang, JY
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2002, 41 (21) : 5139 - 5144
  • [36] Synthesis of propylene glycol and dimethyl carbonate using polymer-supported catalysts
    Zhu, H
    Chen, LB
    Jiang, YY
    CHINESE CHEMICAL LETTERS, 1996, 7 (06) : 519 - 522
  • [37] SYNTHESIS　OF　PROPYLENE　GLYCOL　AND　DIMETHYL　CARBONATE　USING　POLYMER－SUPPORTED　CATALYSTS
    Hong ZHU
    Li Ban CHEN(Guangzhou Institute of Chemistry
    Chinese Chemical Letters, 1996, (06) : 519 - 522
  • [38] Effect of ZnCl2 Co-catalyst in the Synthesis of Dimethyl Carbonate from Ethylene Carbonate and Methanol by Using Base Catalysts
    Kim, Dong-Woo
    Park, Moon-Seok
    Kim, Moon-Il
    Park, Dae-Won
    KOREAN CHEMICAL ENGINEERING RESEARCH, 2012, 50 (02): : 217 - 222
  • [39] CeO2-ZrO2 solid solution catalyst for selective synthesis of dimethyl carbonate from methanol and carbon dioxide
    Tomishige, K
    Furusawa, Y
    Ikeda, Y
    Asadullah, M
    Fujimoto, K
    CATALYSIS LETTERS, 2001, 76 (1-2) : 71 - 74
  • [40] Catalytic behavior of calcium oxide for synthesis of dimethyl carbonate from propylene carbonate and methanol near room temperature
    Wei, T
    Wang, M
    Wei, W
    Sun, YH
    Zhong, B
    UTILIZATION OF GREENHOUSE GASES, 2003, 852 : 138 - 158
12345