Pressure-Induced Water Insertion in Synthetic Clays

被引：22

作者：

You, Shujie ^{[1
]}

Kunz, Daniel ^{[2
]}

Stoeter, Matthias ^{[2
]}

Kalo, Hussein ^{[2
]}

Putz, Bernd ^{[2
]}

Breu, Josef ^{[2
]}

Talyzin, Alexandr V. ^{[1
]}

机构：

[1] Umea Univ, Dept Phys, S-90187 Umea, Sweden

[2] Univ Bayreuth, Lehrstuhl Anorgan Chem 1, D-95447 Bayreuth, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 14期

关键词：

clays; high pressures; intercalations; X-ray diffraction; GRAPHITE OXIDE; CHARGE HOMOGENEITY; HYDRATION; MINERALS; ORIGIN;

D O I：

10.1002/anie.201210060

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A high-pressure study of a synthetic smectite (Na-fluorohectorite) immersed in liquid media was performed using in situ synchrotron X-ray diffraction in a diamond anvil cell. A reversible phase transition because of the insertion of an additional water layer was observed for this material at 1.7 GPa. No similar transition was found when methanol was used as a pressure medium (see picture). © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3891 / 3895

页数：5

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