Copper hexacyanoferrate as cathode material for hydrogen peroxide fuel cell

被引：22
|
作者：
Martins, R. F. [1 ]
Martins, D. A. A. [1 ]
Costa, L. A. C. [1 ]
Matencio, T. [1 ]
Paniago, R. M. [2 ]
Montoro, L. A. [1 ]
机构：
[1] Univ Fed Minas Gerais, Dept Quim, ICEx, BR-31270901 Belo Horizonte, MG, Brazil
[2] Univ Fed Minas Gerais, Dept Fis, ICEx, BR-31270901 Belo Horizonte, MG, Brazil
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2020年 / 45卷 / 47期
关键词：
Fuel cell; Hydrogen peroxide; Hexacyanoferrate; Cathode; PRUSSIAN BLUE; ELECTROCHEMICAL REDUCTION; CARBON; ELECTRODES; H2O2; FILM; PERFORMANCE; COMPLEX; NICKEL; ANODE;
D O I：
10.1016/j.ijhydene.2020.01.077
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The current need for handheld electronic devices with high energy autonomy has amplified research into clean and mobile energy source developments. Among suitable and promising technologies for this application, fuel cells, FCs are highlighted because of their minimal emission of pollutants and high efficiency. One type of FCs that has yet to be studied is the hydrogen peroxide/direct hydrogen peroxide fuel cell (DPPFCs). The present work is dedicated to the development of DPPFCs of one compartment using copper hexacyanoferrates (CuHCFs) as cathodic material and a Ni grid as anodic material. CuHCFs containing Fe-II and/or Fe-III were synthesized, characterized and their electrocatalyst performances were compared in 0.1 mol L-1 HCl and 0.5 mol L-1 H2O2. The maximum power densities reached for the CuFeII was 8.3 mW cm(-2) and for the CuFeIIFeIII was 2.9 mW cm(-2). The CuHCFs cathode materials show promising results, standing out as innovative materials for such an application. (c) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：25708 / 25718
页数：11
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