Diamines having a C2 symmetry.: Synthesis and application as ligands in the hydrogenation of prochiral substrates over rhodium complexes

被引：16

作者：

Shainyan, BA ^{[1
]}

Ustinov, MV ^{[1
]}

Bel'skii, VK ^{[1
]}

Nindakova, LO ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Div, Irkutsk Inst Chem, Irkutsk 664033, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 38卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1023/A:1015367111704

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral diamines having a C-2 symmetry, (4S,5S)-2,2-dimethyl-4,5-bis(aminomethyl)-1,3-dioxolane and (5S,5'S)-2,2,2',2'-tetramethyl-3,3'-diphenyl-5,5'-bioxazolidine, were synthesized on the basis of (+)-(2R,3R)-tartaric acid. Their structure was proved by X-ray analysis. The products were used as ligands in rhodium catalyst for enantioselective hydrogenation of alpha-acetamidocinnamic and itaconic acids.

引用

页码：104 / 110

页数：7

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