Double-Metal Complexation of Heterogels Containing Cyanobacterial Polysaccharides

被引：7
|
作者：
Okajima, Maiko K. [1 ]
Quyen Thi Le Nguyen [1 ]
Nakamura, Masatoshi [1 ]
Ogawa, Tetsuya [2 ]
Kurata, Hiroki [2 ]
Kaneko, Tatsuo [1 ]
机构：
[1] Japan Adv Inst Sci & Technol, Sch Mat Sci, Nomi, Ishikawa 9231292, Japan
[2] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2013年 / 128卷 / 01期
关键词：
cyanobacteria; gels; metal complexation; polysaccharides; rare earth metals; RECOVERY; IONS; NEODYMIUM; MAGNET;
D O I：
10.1002/app.38261
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Cryogenic-transmission electron microscopy of metal complexes with cyanobacterial polysaccharides, sacran, extracted from Aphanothece sacrum biomaterials reveals that Nd3+ complexes form networks composed of thick strings with a thickness ranging 10-20 nm while Fe2+ ones make dense entanglement of very thin strings. When Fe2+ and Nd3+ double complexation occurs, dense nanonetworks composed of thick strings with a thickness around 10 nm are formed. Next we prepared heterogels by crosslinking poly(vinyl alcohol) chains in the presence of sacran and investigated the effects of double complexation on metal sorption. The amount of Nd3+ sorbed into the heterogels in the 1 : 1 miscible solution of Fe2+ and Nd3+ is higher than that in the solution containing only Nd3+, suggesting that Fe2+ assists the Nd3+ sorption. In addition, it is found that the amount of sorbed Nd3+ is much higher than that of sorbed Fe2+ even in the acidic condition of pH 2. (C) 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 128: 676-683, 2013
引用
收藏
页码：676 / 683
页数：8
相关论文
共 50 条
  • [31] Ring-opening copolymerization of maleic anhydride with propylene oxide by double-metal cyanide
    Hua, ZJ
    Qi, GR
    Chen, S
    JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 93 (04) : 1788 - 1792
  • [32] A radial double-metal bias-free THz emitter for coaxial cable transmission
    Gow, Paul C.
    Carthy, Joanna L.
    Berry, Sam A.
    Apostolopoulos, Vasilis
    2017 42ND INTERNATIONAL CONFERENCE ON INFRARED, MILLIMETER, AND TERAHERTZ WAVES (IRMMW-THZ), 2017,
  • [33] Measurement of the spatial resolution of double-sided double-metal AC-coupled silicon microstrips detectors
    Brenner, R.
    Harr, R.
    Rudge, A.
    Santos, D.
    Straver, J.
    Weilhammer, P.
    Czermark, a.
    Gadomski, S.
    Turala, M
    Bonvicini, V.
    Kucewicz, W.
    Masciocchi, S.
    Vegni, G.
    Peisert, A.
    Ardelan, J.
    Hrisoho, A.
    Nuclear Instruments and Methods in Physics Research, Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, 1993, A326 (1-2) : 189 - 197
  • [34] FIELD INVERSION GENERATED IN THE CMOS DOUBLE-METAL PROCESS DUE TO PETEOS AND SOG INTERACTIONS
    HSU, SL
    LIU, LM
    FANG, CH
    YING, SL
    CHEN, TL
    LIN, MS
    CHANG, CY
    IEEE TRANSACTIONS ON ELECTRON DEVICES, 1993, 40 (01) : 49 - 53
  • [35] Sequence structure of polyether catalyzed by Fe–Zn double-metal cyanide complex catalysts
    Su Chen
    Li Chen
    Colloid and Polymer Science, 2003, 281 : 288 - 291
  • [36] Double-metal waveguide λ≃19 μm quantum cascade lasers grown by metal organic vapour phase epitaxy
    Fan, J. A.
    Belkin, M. A.
    Troccoli, M.
    Corzine, S.
    Bour, D.
    Hoefler, G.
    Capasso, F.
    ELECTRONICS LETTERS, 2007, 43 (23) : 1284 - 1285
  • [37] Influence of the facet type on the performance of terahertz quantum cascade lasers with double-metal waveguides
    Brandstetter, Martin
    Krall, Michael
    Deutsch, Christoph
    Detz, Hermann
    Andrews, Aaron M.
    Schrenk, Werner
    Strasser, Gottfried
    Unterrainer, Karl
    APPLIED PHYSICS LETTERS, 2013, 102 (23)
  • [38] Determination of the binding parameters of epoxide substrates to Fe/Cd double-metal cyanide complexes
    Billodeaux, D
    Darensbourg, DJ
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 225 : U71 - U72
  • [39] Fe-Zn double-metal cyanide complexes as novel, solid transesteritication catalysts
    Srivastava, R.
    Srinivas, D.
    Ratnasamy, P.
    JOURNAL OF CATALYSIS, 2006, 241 (01) : 34 - 44
  • [40] Novel amorphous-silicon-based double-metal antifuse with barrier enhancement layer
    Fang, Yeau-Kuen
    Lee, Kuen-Hsien
    Chen, Fu-Yuan
    Hwang, Jun-Dar
    Japanese Journal of Applied Physics, Part 1: Regular Papers & Short Notes & Review Papers, 1995, 34 (4 A): : 1736 - 1740
12345