Cobalt-Catalyzed Annulation Reactions via C-H Bond Activation

被引：128

作者：

Prakash, Sekar ^{[1
]}

Kuppusamy, Ramajayam ^{[1
]}

Cheng, Chien-Hong ^{[1
]}

机构：

[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan

来源：

CHEMCATCHEM | 2018年 / 10卷 / 04期

关键词：

annulation; C-H activation; cobalt; heterocycles; reductive elimination; REDOX-NEUTRAL SYNTHESIS; CARBON-HYDROGEN BONDS; REGIOSELECTIVE INTERMOLECULAR ANNULATION; QUATERNARY AMMONIUM-SALTS; TRACELESS DIRECTING GROUP; CROSS-COUPLING REACTIONS; COBALT(III)-CATALYZED SYNTHESIS; EFFICIENT SYNTHESIS; ARYL SULFONAMIDES; ALIPHATIC AMIDES;

D O I：

10.1002/cctc.201701559

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Considerable research attention has been directed towards the use of first-row transition metals in organic synthesis. The more abundant, and less expensive cobalt is considered to be an effective alternative for expensive second and third-row noble metals, especially in C-H bond functionalization reactions. In this Minireview, we will summarize the features, and recent achievements of the Co-catalyzed directing group assisted C-H activation/cyclization reactions and their mechanistic insights.

引用

页码：683 / 705

页数：23

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