Regularities of formation of binary intermetallic compounds between transition and non-transition elements

被引：0
|
作者：
Yao, LX [1 ]
Yang, J [1 ]
Ye, CZ [1 ]
Chen, NY [1 ]
机构：
[1] Shanghai Jiao Tong Univ, Inst Image Proc & Pattern Recognit, Shanghai 200030, Peoples R China
来源：
CHINESE SCIENCE BULLETIN | 2001年 / 46卷 / 21期
关键词：
transition metal; non-transition metal; intermetallic compound; formation criterion;
D O I：
10.1007/BF02900566
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
A four-parameter model based on the extended Miedema's cellular model of alloy phases and pattern recognition methods has been used to study the regularities Of the formation of binary intermetallic compounds between transition element and non-transition element. The formation criterion can be expressed as some inequities of electronegativity phi, the valence electron density in Wagner-Seitz cell n(ws)(1/3), Pauling's metallic radius R and the number of valence electrons in atom Z or their functions. According to these empirical criterions, the "unknown" binary alloy system can be predicted, the predicted result is better than that of Miedema's two-parameter model.
引用
收藏
页码：1845 / 1848
页数：4
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