A homochiral metal-organic material with permanent porosity, enantioselective sorption properties, and catalytic activity

被引：592

作者：

Dybtsev, DN

Nuzhdin, AL

Chun, H

Bryliakov, KP

Talsi, EP

Fedin, VP

Kim, K

机构：

[1] Pohang Univ Sci & Technol, Natl Creat Res Initiat Ctr Smart Supramol, Pohang 790784, South Korea

[2] Pohang Univ Sci & Technol, Dept Chem, Div Mol & Life Sci, Pohang 790784, South Korea

[3] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia

[4] Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 06期

关键词：

chirality; heterogeneous catalysis; metal-organic frameworks; microporous materials; sorption;

D O I：

10.1002/anie.200503023

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A handy approach: A new synthetic approach starting from readily available chemicals successfully produces a robust homochiral metal-organic microporous framework. The material exhibits size- and enantioselective guest-sorption properties (see picture), as well as remarkable catalytic activity with size- and chemoselectivity, and high conversion in the oxidation of thioethers to sulfoxides. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：916 / 920

页数：5

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