A nanotubular metal-organic framework with permanent porosity: structure analysis and gas sorption studies

被引：88

作者：

Ma, Shengqian ^{[1
]}

Simmons, Jason M. ^{[3
]}

Yuan, Daqiang ^{[2
]}

Li, Jian-Rong ^{[2
]}

Weng, Wei ^{[1
]}

Liu, Di-Jia ^{[1
]}

Zhou, Hong-Cai ^{[2
]}

机构：

[1] Argonne Natl Lab, Chem Sci & Engn Div, Argonne, IL 60439 USA

[2] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

[3] Natl Inst Stand & Technol, Ctr Neutron Res, Gaithersburg, MD 20899 USA

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 27期

关键词：

HIGH H-2 ADSORPTION; HYDROGEN STORAGE; METHANE ADSORPTION; SELECTIVE SORPTION; THERMAL-STABILITY; CARBON-DIOXIDE; SURFACE-AREA; MOLECULES; DESIGN; SEPARATION;

D O I：

10.1039/b906605e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A nanotubular metal-organic framework, PCN-19, was constructed based on a mu(3)-oxo-trinickel basic carboxylate secondary building unit (SBU) and the 9,10-anthracenedi-carboxylate ligand; its permanent porosity was confirmed by N-2 adsorption isotherms, and its H-2 storage performances were evaluated under both low and high pressures at 77 K.

引用

页码：4049 / 4051

页数：3

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