Symmetric bis-substituted and asymmetric mono-substituted nitridotechnetium complexes with heterofunctionalized phosphinothiolate ligands

被引：14

作者：

Bolzati, C

Malagò, E

Boschi, A

Cagnolini, A

Porchia, M

Bandoli, G ^{[1
]}

机构：

[1] Univ Padua, Dipartimento Sci Farmaceut, I-35131 Padua, Italy

[2] Univ Ferrara, Dipartimento Med Clin & Sperimentale, Nucl Med Lab, I-44100 Ferrara, Italy

[3] CNR, ICTIMA, I-35127 Padua, Italy

来源：

NEW JOURNAL OF CHEMISTRY | 1999年 / 23卷 / 08期

关键词：

D O I：

10.1039/a903679b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mixed bidentate ligand 2-(dicyclohexylphosphino)-ethanethiol (HL) reacts with labile nitrido-Tc precursors to afford a rare example of an asymmetric monosubstituted species [TcN(L)Cl(PPh3)], 1, along with the symmetric bis-substituted complex [TcN(L)(2)], 2. The latter compound, as assessed by TLC and HPLC chromatography, was found to possess the same molecular structure as the agent produced at the 'non carrier added' level utilizing the Tc-99m nuclear isomer.

引用

页码：807 / 809

页数：3

共 50 条

[31] HYDROSILYLATION OF ACETYLENE AND ITS MONO-SUBSTITUTED IN THE PRESENCE OF 1-VINYLAZOLE COMPLEXES WITH PLATINUM AND RHODIUM HALIDES
KOPYLOVA, LI
IVANOVA, ND
VOROPAEV, VN
SATSUK, EN
SHERGINA, NI
SHERSTYANNIKOVA, LV
VORONKOV, MG
ZHURNAL OBSHCHEI KHIMII, 1988, 58 (04): : 806 - 811
[32] Copper(II) and zinc(II) complexes of mono- and bis-1,2,3-triazole-substituted heterocyclic ligands
Juraj, Natalija Pantalon
Krklec, Marko
Novosel, Tiana
Peric, Berislav
Vianello, Robert
Raic-Malic, Silvana
Kirin, Srecko, I
DALTON TRANSACTIONS, 2020, 49 (26) : 9002 - 9015
[33] Bis- and mono-substituted Chalcones exert anti-feedant and toxic effects on fall armyworm Spodoptera frugiperda
Devi, Ahanthem Priyanca
Alsulimani, Ahmad
Hidalgo, Jose R.
Neske, A.
Sayyed, R. Z.
Hassan, Montaser
Ameta, Keshav Lalit
Elshazly, Hayam
SAUDI JOURNAL OF BIOLOGICAL SCIENCES, 2021, 28 (10) : 5754 - 5759
[34] Tandem aminoxylation-allylation reactions: a rapid, asymmetric conversion of aldehydes to mono-substituted 1,2-diols
Zhong, GF
CHEMICAL COMMUNICATIONS, 2004, (05) : 606 - 607
[35] Ruthenium complexes with asymmetric hydroxy- and methoxy-substituted bipyridine ligands
Benson, Kaitlyn R.
Stash, Jaqueline
Moffa, Katherine L.
Schmehl, Russell H.
Dudley, Timothy J.
Paul, Jared J.
POLYHEDRON, 2021, 205
[36] A pentametallic Co5L4 architecture constructed from bis-substituted phosphate-based ligands
Ward, Jas S.
Kruger, Paul E.
CRYSTENGCOMM, 2024, 26 (26) : 3459 - 3462
[37] A new substituted bis(vic-dioxime) of its mono-and dinuclear complexes
Güngör, O
Canpolat, E
Kaya, M
POLISH JOURNAL OF CHEMISTRY, 2003, 77 (04) : 403 - 410
[38] Preparations and structures of a series of novel, mono-substituted cis,cis-1,3,5-triaminocyclohexane-based complexes
Greener, B
Cronin, L
Wilson, GD
Walton, PH
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (03): : 401 - 403
[39] TRANSITION-METAL CARBYNE COMPLEXES .86. SYNTHESIS OF MONO-TRIMETHYLPHOSPHANE-SUBSTITUTED, BIS-TRIMETHYLPHOSPHANE-SUBSTITUTED AND TRIS-TRIMETHYLPHOSPHANE-SUBSTITUTED DIETHYLAMINOCARBYNE COMPLEXES OF TUNGSTEN
FILIPPOU, AC
FISCHER, EO
OKUDA, J
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 339 (03) : 309 - 321
[40] Molecular recognition of bases and nucleosides by mono-substituted mononuclear complexes of 1,4,7,10-tetraaza-cyclododecane
Xiang, QX
Yu, XQ
Wu, J
Liu, PY
Xia, CQ
Xie, RG
CHINESE JOURNAL OF CHEMISTRY, 2003, 21 (07) : 910 - 916

← 1 2 3 4 5 →