Oxygen-deficient strontium cobaltate, SrCoO2.64

被引:14
|
作者
Nakatsuka, A [1 ]
Yoshiasa, A
Nakayama, N
Mizota, T
Takei, H
机构
[1] Yamaguchi Univ, Fac Engn, Dept Adv Mat Sci & Engn, Ube, Yamaguchi 7558611, Japan
[2] Osaka Univ, Grad Sch Sci, Dept Earth & Space Sci, Toyonaka, Osaka 5600043, Japan
关键词
D O I
10.1107/S0108270104006134
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Single crystals of strontium cobaltate, SrCoO3-x, have been grown by the floating-zone method in an oxygen flow. The compound crystallizes with the cubic perovskite structure, with Pm (3) over barm symmetry, as determined by X-ray diffraction. Refinement of the O-atom site occupancy yields the chemical composition SrCoO2.64 [ x = 0.36 ( 3)]. The anisotropic displacement ellipsoids of the O atoms suggest that their positional disorder occurs in a direction perpendicular to that of the Co - O bonds.
引用
收藏
页码:I59 / I60
页数:2
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