Mixed-ligand cluster [Mo3S4(Dtp)2(μ-AcO)Cl(Me2Bipy)]: Synthesis and structure

被引：10

作者：

Gushchin, A. L. ^{[1
,2
]}

Laricheva, Yu. A. ^{[1
]}

Piryazev, D. A. ^{[1
]}

Sokolov, M. N. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2014年 / 40卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

RAY CRYSTAL-STRUCTURES; MOLYBDENUM CLUSTERS; CUBOIDAL CLUSTERS; COMPLEXES; TRINUCLEAR; MO; MECHANISM; MO3S4; PHENANTHROLINE; DERIVATIVES;

D O I：

10.1134/S1070328414010023

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mixed-ligand cluster [Mo3S4(Dtp)(2)(mu-AcO)Cl(Me(2)Bipy)] center dot CHCl3 (I center dot CHCl3), where Dtp is (EtO)(2)PS2, was synthesized by the reaction of the molybdenum aqua complex [Mo3S4(H2O)(9)](4+) with 4,4'-dimethyl-2,2'-bipyridine (Me(2)Bipy) and phosphorus sulfide (P4S10) in ethanol followed by chromatographic separation on silica gel and crystallization in the presence of acetic acid. The crystal structure of I center dot CHCl3 was determined by X-ray diffraction analysis. The synthesized compound was characterized by the IR and NMR spectra and elemental analysis. The electronic structure of the synthesized compound was established, and its electrochemical behavior in a solution was studied.

引用

页码：5 / 9

页数：5

共 50 条

[21] A new function of the (μ3-S) ligand in an Fe4S4 cluster:: Synthesis and structure of the high-nuclearity Mo/Fe/S cluster, Fe(DMF)Cl(Cl4-cat)2Mo2Fe2S4(PEt3)2ClFe4S4(PEt3)3(CO)6Cl
Han, JH
Coucouvanis, D
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (45) : 11304 - 11305
[22] Synthesis and crystal structure of cubane-type molybdenum cluster complex Mo4S4(DTP)4[μ-SOP(OEt)2]2
Qin, YY
Li, ZJ
Kang, Y
Wu, L
Yao, YG
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2002, 21 (03) : 303 - 308
[23] (d-p)π共轭作用对簇合物Mo2S4（dtp）2和Mo3S4（dtp）4·Py电子光谱的影响
程文旦
黄锦顺
郭国聪
卢嘉锡
结构化学, 1993, (06) : 445 - 448
[24] Synthesis and Crystal Structure of Cubane-type Molybdenum Cluster Complex Mo4S4（DTP）4[μ-SOP（OEt）2]2
QIN Ye-Yan LI Zhao-Ji KANG Yao WU Ling YAO Yuan-Gen② (State Key Laboratory of Structural Chemistry
结构化学, 2002, (03) : 303 - 308
[25] Synthesis and crystal and molecular structure of mixed-ligand complexes Cd(2,2′-Bipy)(i-PrOCS2)2 and(2,2′-Bipy)(i-BuOCS2)2
Larionov, S. V.
Glinskaya, L. A.
Leonova, T. G.
Klevtsova, R. F.
JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 46 (06) : 1023 - 1030
[26] Synthesis and crystal and molecular structure of mixed-ligand complexes Cd(2,2′-Bipy)(i-PrOCS2)2 and (2,2′-Bipy)(i-BuOCS2)2
S. V. Larionov
L. A. Glinskaya
T. G. Leonova
R. F. Klevtsova
Journal of Structural Chemistry, 2005, 46 : 1023 - 1030
[27] THE REPLACEMENT REACTION OF TRINUCLEAR MOLYBDENUM CLUSTERS - SYNTHESIS AND CRYSTAL-STRUCTURE OF 2 MOLYBDENUM CLUSTERS [MO3S4(DTC)4(DMF)](ETOH) AND [MO3S4(DTC)4(PY)](PY)2(H2O)
HUANG, MD
LU, SF
HUANG, JQ
HUANG, JL
ACTA CHIMICA SINICA, 1989, 47 (02) : 121 - 127
[28] Synthesis and crystal structure of all ionic cluster {[Mo-3(mu(3)-O)(mu-S)(3)(dtp)(3)(py)(3)][CdI(dtp)(2)]}
Lu, SF
Huang, JQ
Huang, XY
Wu, QJ
CHINESE JOURNAL OF CHEMISTRY, 1997, 15 (04) : 296 - 303
[29] Ligand substitution in the cluster complex [Mo3S7Cl6]2−: Synthesis and crystal structure of (Et4N)[Mo3S7Cl5(CH3CN)]
S. A. Adonin
A. V. Virovets
M. N. Sokolov
V. P. Fedin
Russian Journal of Coordination Chemistry, 2010, 36 : 871 - 875
[30] SYNTHESIS AND STRUCTURE OF TETRANUCLEAR MOLYBDENUM CLUSTER COMPOUND[Mo4S4（μ-O2CC6H5）2（dtp）4]
Hong Hui ZHUANG Ding Ming WU Jian Quan HUANG Jin Ling HUANG Fuzhou Laboratory of Structure Chemistry and Fujian Institute of Research on the Structure of Matter
ChineseChemicalLetters, 1991, (07) : 553 - 554

← 1 2 3 4 5 →