Mixed-ligand cluster [Mo3S4(Dtp)2(μ-AcO)Cl(Me2Bipy)]: Synthesis and structure

被引：10
|
作者：
Gushchin, A. L. [1 ,2 ]
Laricheva, Yu. A. [1 ]
Piryazev, D. A. [1 ]
Sokolov, M. N. [1 ,2 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2014年 / 40卷 / 01期
基金：
俄罗斯基础研究基金会;
关键词：
RAY CRYSTAL-STRUCTURES; MOLYBDENUM CLUSTERS; CUBOIDAL CLUSTERS; COMPLEXES; TRINUCLEAR; MO; MECHANISM; MO3S4; PHENANTHROLINE; DERIVATIVES;
D O I：
10.1134/S1070328414010023
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Mixed-ligand cluster [Mo3S4(Dtp)(2)(mu-AcO)Cl(Me(2)Bipy)] center dot CHCl3 (I center dot CHCl3), where Dtp is (EtO)(2)PS2, was synthesized by the reaction of the molybdenum aqua complex [Mo3S4(H2O)(9)](4+) with 4,4'-dimethyl-2,2'-bipyridine (Me(2)Bipy) and phosphorus sulfide (P4S10) in ethanol followed by chromatographic separation on silica gel and crystallization in the presence of acetic acid. The crystal structure of I center dot CHCl3 was determined by X-ray diffraction analysis. The synthesized compound was characterized by the IR and NMR spectra and elemental analysis. The electronic structure of the synthesized compound was established, and its electrochemical behavior in a solution was studied.
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页码：5 / 9
页数：5
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