New strongly coupled dinuclear metal centres in organometallic s-indacene complexes

被引：21

作者：

Cary, DR ^{[1
]}

Webster, CG ^{[1
]}

Drewitt, MJ ^{[1
]}

Barlow, S ^{[1
]}

Green, JC ^{[1
]}

OHare, D ^{[1
]}

机构：

[1] UNIV OXFORD,INORGAN CHEM LAB,OXFORD OX1 3QR,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 10期

关键词：

D O I：

10.1039/a700297a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complexes cis-[{Fe(CO)(3)}(2)L] and cis-[{Co(CO)(2)}(2)L] are prepared from 1,3,5,7-tetra-tert-butyl-s-indacene; in solution, the diiron complexes exhibit very strong electron-electron coupling between iron centres as evidenced by a 810 mV separation between the 0/+ and +/2+ redox waves.

引用

页码：953 / 954

页数：2

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