Rings and linear polymers formed by addition of silver perchlorate to trans-[Pt(C CR)(2)(PMe(2)Ph)(2)] (R=Bu(t),H)

被引：33
|
作者：
Yamazaki, S
Deeming, AJ
Speel, DM
Hibbs, DE
Hursthouse, MB
Malik, KMA
机构：
[1] KOCHI GAKUEN COLL,CHEM LAB,KOCHI 780,JAPAN
[2] UNIV WALES COLL CARDIFF,SCH CHEM & APPL CHEM,CARDIFF CF1 3TB,S GLAM,WALES
来源：
CHEMICAL COMMUNICATIONS | 1997年 / 02期
关键词：
D O I：
10.1039/a607358a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Addition of AgClO4 to trans-[Pt(C=CR)(2)(PMe(2)Ph)(2)] (R = Bu(t), H) gives 1:1 adducts of the general formula trans-[PtAg(ClO4)(mu-C=CR)(2)(PMe(2)Ph)(2)] which are cyclic dimers when R = Bu(t) (ClO4- not coordinated) or linear polymers when R = H (ClO4- coordinated to silver).
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页码：177 / 178
页数：2
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