Synthesis of Polyhydroquinoline, 2,3-Dihydroquinazolin-4(1H)-one, Sulfide and Sulfoxide Derivatives Catalyzed by New Copper Complex Supported on MCM-41

被引:62
|
作者
Tamoradi, Taiebeh [1 ]
Ghadermazi, Mohammad [1 ]
Ghorbani-Choghamarani, Arash [2 ]
机构
[1] Univ Kurdistan, Dept Chem, Fac Sci, Sanandaj, Iran
[2] Ilam Univ, Dept Chem, Fac Sci, POB 69315516, Ilam, Iran
关键词
MCM-41; Copper; Polyhydroquinoline; 2,3-Dihydroquinazolin-4(1H)-one; Sulfide; Sulfoxide; SCHIFF-BASE COMPLEX; MAGNETICALLY RECOVERABLE CATALYST; FUNCTIONALIZED NANOPOROUS MCM-41; ADHESION MOLECULE-1 INTERACTION; P-ARYLTHIO CINNAMIDES; SELECTIVE OXIDATION; FE3O4; NANOPARTICLES; CARBON-DISULFIDE; 5-SUBSTITUTED TETRAZOLES; ORGANIC SEMICONDUCTORS;
D O I
10.1007/s10562-018-2311-x
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A simple, efficient and less expensive protocol for the synthesis of Cu(II) immobilized on MCM-41@Serine has been reported. This nanohybrid material was carefully characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy, inductively coupled plasma optical emission spectroscopy, X-ray diffraction, TEM, thermal gravimetric analysis, and N-2 adsorption and desorption. The obtained nanostructured compound were also employed as a green, efficient, heterogeneous and reusable catalytic system for the synthesis of polyhydroquinoline, 2,3-dihydroquinazolin-4(1H)-one, sulfide and sulfoxide derivatives. High surface area, convenient recovery and reusability for several times without any significant loss of activity, the use of a commercially available, eco-friendly, cheap and chemically stable reagents, good reaction times, simple practical methodology and ease of use all make Cu(II) immobilized on MCM-41@Serine a promising candidate for potential applications in some organic reactions; makes this protocol both attractive and economically viable. MCM-41 nanostructured was prepared via simple and versatile procedure and directly immobilized with a new type of Cu-serine complex. After characterization of this catalyst, the catalytic activity of this nanostructure compound has been investigated for the synthesis of polyhydroquinoline, 2,3-dihydroquinazolin-4(1H)-one, sulfide and sulfoxide derivatives. [GRAPHICS]
引用
收藏
页码:857 / 872
页数:16
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