Structures of Sb(OC6H3Me2-2,6)3 and Sb(OEt)5•NH3:: The first authenticated monomeric Sb(OR)n (n=3, 5)

被引：23

作者：

Horley, GA

Mahon, MF

Molloy, KC ^{[1
]}

Venter, MM

Haycock, PW

Myers, CP

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[2] Univ Keele, Sch Chem & Phys, Lennard Jones Labs, Birchall Ctr Inorgan Chem & Mat Sci, Keele ST5 5BG, Staffs, England

来源：

INORGANIC CHEMISTRY | 2002年 / 41卷 / 06期

关键词：

D O I：

10.1021/ic0106726

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first monomeric antimony alkoxides, Sb(OC6H3Me2)(3) (1) and Sb(OEt)(5).NH3 (2), have been crystallographically characterized. The former adopts a trigonal pyramidal geometry, while the latter is octahedral about antimony; hydrogen bonding between NH3 and SbOEt groups in Sb(OEt)(5).NH3 creates a one-dimensional lattice arrangement. Reaction of pyridine with SbCl5 in EtOH/hexane yields the salt [Hpy(+)](9)[Sb2Cl115-][Cl-](4) (3), which has also been crystallographically characterized. Crystallographic data: 1, C24H27O3Sb, a = 10.9080(2), b = 11.9660(2), c = 17-7260(4) Angstrom, alpha = 109.740(1)degrees, monoclinic P2(1)/c (unique axis a), Z = 4; 2, C10H28NO5Sb, a = 7.7220(l), b = 19.0700(2), c = 21.6800(3) Angstrom, 93.4960(7)degrees, monoclinic P2(1)/c, Z = 8; 3, C45H54Cl15N9Sb2, a 13.4300(2), b = 14.4180(2), c = 17.4180(3) Angstrom, alpha = 82.7650(7), beta = 77.5570(7), gamma = 70.7670(7)degrees, triclinic Z = 2.

引用

页码：1652 / 1657

页数：6

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