Half-sandwich ruthenium complexes for the controlled radical polymerisation of vinyl monomers

被引：31
|
作者：
Tutusaus, O
Delfosse, S
Simal, F
Demonceau, A
Noels, AF
Núñez, R
Viñas, C
Teixidor, F
机构：
[1] Univ Liege, Lab Macromol Chem & Organ Catalysis, B-4000 Liege, Belgium
[2] UAB, CSIC, Inst Ciencia Mat, Barcelona 08193, Spain
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 11期
关键词：
homogeneous catalysis; olefins; polymerisations; radical reactions; ruthenium and compounds;
D O I：
10.1016/S1387-7003(02)00608-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Ruthenium complexes of the type [RuX (Cp-#) (PPh3)(2)] (X = Cl and H; Cp-# = Cp, Cp*, indenyl, and carboranyl) catalyse the radical polymerisation of styrene and n-butyl acrylate, and both the catalyst activity and the degree of control of the polymerisation strongly depend on the Cp-# ligand and the monomer. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：941 / 945
页数：5
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