Crystal Structure of Binuclear Bismuth Complex [H2dabco]2[Bi2Br10]•4H2O

被引：4
|
作者：
Kovalenko, E. A. [1 ]
Kochelakov, D. V. [1 ,2 ]
Samsonenko, D. G. [1 ,2 ]
Fedin, V. P. [1 ,2 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
[2] Novosibirsk State Univ, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2018年 / 59卷 / 01期
关键词：
synthesis; bismuth; dabco; single crystal X-ray diffraction analysis; crystal structure; HALIDE-COMPLEXES; SOLVATION; BI(III); HYBRIDS;
D O I：
10.1134/S0022476618010304
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Binuclear bismuth complex [H(2)dabco](2)[Bi2Br10]center dot 4H(2)O is obtained by heating the solution of bismuth bromide with diazabicyclo[2.2.2]octane in 2 M HBr. The structure of the complex is determined by single crystal X-ray diffraction. The compound is characterized by IR and Raman spectroscopy, powder X-ray diffraction, and elemental analysis.
引用
收藏
页码：193 / 196
页数：4
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