Pb2B5O9Cl: a chloride borate with second harmonic generation effect

被引：37
|
作者：
Chen, Zhaohui [1 ,2 ]
Pan, Shilie [1 ]
Yang, Zhihua [1 ]
Dong, Xiaoyu [1 ,3 ]
Su, Xin [1 ]
Yang, Yun [1 ]
机构：
[1] Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China
[2] Xinjiang Univ, Phys & Chem Detecting Ctr, Urumqi 830046, Peoples R China
[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
JOURNAL OF MATERIALS SCIENCE | 2013年 / 48卷 / 06期
基金：
中国国家自然科学基金;
关键词：
NONLINEAR-OPTICAL SUSCEPTIBILITIES; BOND-VALENCE PARAMETERS; X-RAY-DIFFRACTION; DENSITY-OF-STATES; CRYSTAL-STRUCTURE; SINGLE-CRYSTAL; BAND-STRUCTURE; FEATURES; BABIBO4;
D O I：
10.1007/s10853-012-7051-5
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Single crystal of Pb2B5O9Cl with sizes up to 25 x 6 x 2 mm(3) has been obtained successfully using PbCl2-H3BO3 flux system by the high temperature solution method for the first time. It crystallizes in noncentrosymmetric orthorhombic space group Pnn2 (No. 34). It produces second harmonic generation (SHG) intensity about 4 times that of KH2PO4 (KDP) and is phase matchable. The origin and magnitude of the strong SHG effect was discussed. Band structures, density of states, and dipole moment calculations were calculated.
引用
收藏
页码：2590 / 2596
页数：7
相关论文
共 50 条
  • [41] INCORPORATION OF CHROMIUM INTO ALUMINUM BORATE 9AL2O3.2B2O3 (A9B2)
    GARSCHE, M
    TILLMANNS, E
    ALMEN, H
    SCHNEIDER, H
    KUPCIK, V
    EUROPEAN JOURNAL OF MINERALOGY, 1991, 3 (05) : 793 - 808
  • [42] Implications of second harmonic generation for hidden order in Sr2CuO2Cl2
    de la Torre, A.
    Di Matteo, S.
    Hsieh, D.
    Norman, M. R.
    PHYSICAL REVIEW B, 2021, 104 (03)
  • [43] Layered oxide B2S2O9 with a deep-ultraviolet band gap and a strong and robust second-harmonic generation
    Kang, Lei
    Liu, Xiaomeng
    Lin, Zheshuai
    Huang, Bing
    PHYSICAL REVIEW B, 2020, 102 (20)
  • [44] Second harmonic generation and Raman study of second-order nonlinearity in PbO/B2O3 glass
    Xi, YG
    Qi, LJ
    Liu, LY
    Xu, L
    Wang, WC
    Affatigato, M
    Feller, SA
    PHYSICS AND CHEMISTRY OF GLASSES, 2003, 44 (02): : 103 - 105
  • [45] Crystallization, texture and second-harmonic generation in TiO2-BaO-B2O3 glasses
    Feitosa, C. A. C.
    Mastelaro, V. R.
    Zanatta, A. R.
    Hernandes, A. C.
    Zanotto, E. D.
    OPTICAL MATERIALS, 2006, 28 (8-9) : 935 - 943
  • [46] Synthesis and Characterization of the First Tin Fluoride Borate Sn3[B3O7]F with Second Harmonic Generation Response
    Schoenegger, Sandra
    Jantz, Stephan G.
    Saxer, Andreas
    Bayarjargal, Lkhamsuren
    Winkler, Bjoern
    Pielnhofer, Florian
    Hoeppe, Henning A.
    Huppertz, Hubert
    CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (60) : 16036 - 16043
  • [47] THE STRUCTURE OF SODIUM-BORATE NA3[B5O9].H2O
    MENCHETTI, S
    SABELLI, C
    TROSTIFERRONI, R
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (DEC): : 2987 - 2991
  • [48] Na4[B6O9 (OH)3](H2O) Cl: A Deep-Ultraviolet Transparent Nonlinear Optical Borate Chloride with {[B6O9 (OH)3]3-}∞ Chains
    Tang, Ru-Ling
    Huai, Lei
    Liu, Wenlong
    INORGANIC CHEMISTRY, 2023, 62 (25) : 9759 - 9764
  • [49] Li2B4O7 single crystal growth and second harmonic generation coefficients
    Zhang, Xiyan
    Liu, Jinghe
    Li, Zhaohui
    Li, Jianli
    Cao, Ying
    Li, Yanhong
    Guangxue Xuebao/Acta Optica Sinica, 1998, 18 (06): : 824 - 827
  • [50] Polar polymorphism: α- and β-KCsWP2O9nonlinear optical materials with a strong second harmonic generation response
    Baiheti, Tuohetijiang
    Han, Shujuan
    Tudi, Abudukadi
    Yang, Zhihua
    Pan, Shilie
    JOURNAL OF MATERIALS CHEMISTRY C, 2020, 8 (33) : 11441 - 11448
12345