Synthesis of (Z)-1-Aza-1,3-enynes by the Cross-Coupling of Terminal Alkynes with Isocyanides Catalyzed by Rare-Earth Metal Complexes

被引：59

作者：

Zhang, Wen-Xiong ^{[1
,2
,3
]}

Nishiura, Masayoshi ^{[1
]}

Hou, Zhaomin ^{[1
]}

机构：

[1] RIKEN, Organomet Chem Lab, Adv Sci Inst, Wako, Saitama 3510198, Japan

[2] Peking Univ, BNLMS, Beijing 100871, Peoples R China

[3] Peking Univ, Coll Chem, Beijing 100871, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 50期

基金：

日本学术振兴会; 中国国家自然科学基金;

关键词：

cross-coupling; enynes; isocyanides; rare-earth metals; sandwich complexes;

D O I：

10.1002/anie.200804306

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Rare reactivity: A binuclear catalyst intermediate leads to the Z-selective cross-coupling of terminal alkynes with isocyanides to exclusively yield the (Z)-1-aza-1,3-enyne products for the first time (see scheme). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9700 / 9703

页数：4

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