Chain motions of alternating ethylene/propylene copolymers studied solid-state 2H NMR

被引：0
|
作者：
Nakajima, T [1 ]
Akiyama, T [1 ]
Furuya, H [1 ]
机构：
[1] Tokyo Inst Technol, Dept Organ & Polymer Mat, Meguro Ku, Tokyo 1528552, Japan
来源：
POLYMER JOURNAL | 2001年 / 33卷 / 10期
关键词：
ethylene-propylene copolymer; solid-state H-2 NMR; chain motions; linear copolymer; branched copolymer;
D O I：
10.1295/polymj.33.825
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The chain motions of two deuterated alternating ethylene-propylene (EP) copolymers were investigated by solid state nuclear magnetic resonance (NMR) measurements. The effect of the branched side group on the molecular motion of the main chain was also evaluated. The branched side chain group influenced the crystallinity and glass transition temperature of the elastomers affecting the motion of the main chain. For linear copolymer reorientation motion of main chain segments occured at temperature below 40°C.
引用
收藏
页码：825 / 829
页数：5
相关论文
共 50 条
  • [1] Chain Motions of Alternating Ethylene/Propylene Copolymers Studied by Solid-State 2H NMR
    Takeshi Nakajima
    Tsutomu Akiyama
    Hidemine Furuya
    [J]. Polymer Journal, 2001, 33 : 825 - 829
  • [2] Dynamics of a Polyphosphazene Melt Studied by Solid-State 2H NMR
    Koch, Barbara
    Vogel, Michael
    [J]. MACROMOLECULES, 2009, 42 (02) : 531 - 536
  • [3] PHOTOOXIDATION OF ETHYLENE PROPYLENE COPOLYMERS IN THE SOLID-STATE
    ARNAUD, R
    LEMAIRE, J
    JEVANOFF, A
    [J]. POLYMER DEGRADATION AND STABILITY, 1986, 15 (03) : 205 - 218
  • [4] Crystalline Phases in Ethylene Copolymers Studied by Solid-State NMR and DSC
    Gao, Xiuzhi
    Wang, Liying
    Luo, Huan
    Zou, Qin
    Feng, Ningdong
    Feng, Jiwen
    [J]. MACROMOLECULES, 2010, 43 (13) : 5713 - 5722
  • [5] 2H NMR spin relaxation study of the soft segment motion in alternating ethylene-propylene copolymers
    Nakajima, T
    Akiyama, T
    Furuya, H
    [J]. MAGNETIC RESONANCE IN CHEMISTRY, 2002, 40 (02) : 161 - 164
  • [6] 2H Solid-State NMR of Ruthenium Complexes
    Walaszek, Bernadeta
    Adamczyk, Anna
    Pery, Tal
    Xu Yeping
    Gutmann, Torsten
    Amadeu, Nader de Sousa
    Ulrich, Stefan
    Breitzke, Hergen
    Vieth, Hans Martin
    Sabo-Etienne, Sylviane
    Chaudret, Bruno
    Limbach, Hans-Heinrich
    Buntkowsky, Gerd
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (51) : 17502 - 17508
  • [7] 1H NMR relaxation study of chain motions and solid-state ordering in stiff, random copolymers
    Gentzler, M
    Reimer, JA
    [J]. MACROMOLECULES, 1997, 30 (26) : 8365 - 8374
  • [8] Chain dynamics of poly(oxyethylene) in nanotubes of α-cyclodextrin by solid-state 2H NMR
    Girardeau, TE
    Leisen, J
    Beckham, HW
    [J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 2005, 206 (10) : 998 - 1005
  • [9] PHOTODEGRADATION OF HETEROPHASIC ETHYLENE-PROPYLENE COPOLYMERS IN THE SOLID-STATE
    SINGH, RP
    SINGH, A
    [J]. JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1991, A28 (5-6): : 487 - 502
  • [10] Dynamics on the microsecond timescale in hydrous silicates studied by solid-state 2H NMR spectroscopy
    Griffin, John M.
    Miller, Andrew J.
    Berry, Andrew J.
    Wimperis, Stephen
    Ashbrook, Sharon E.
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2010, 12 (12) : 2989 - 2998
12345