Crystal structure of monoclinic modifications of zirconium and hafnium tetrafluoride trihydrates

被引：7
|
作者：
Davidovich, R. L. [1 ]
Pushilin, M. A. [1 ]
Logvinova, V. B. [1 ]
Gerasimenko, A. V. [1 ]
机构：
[1] Russian Acad Sci, Inst Chem, Far Eastern Div, Vladivostok 690022, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2013年 / 54卷 / 03期
关键词：
synthesis; zirconium and hafnium tetrafluorides; X-ray crystallographic analysis; crystal structure; hydrogen bonds;
D O I：
10.1134/S0022476613030104
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The monoclinic modification of ZrF4 center dot 3H(2)O, isostructural to HfF4 center dot 3H(2)O, is synthesized and structurally studied for the first time. Unlike the triclinic modification of ZrF4 center dot 3H(2)O with a dimeric structure, the synthesized compound has a polymer structure formed from infinite chains composed of ZrF6(H2O)(2) groups sharing FaEuro broken vertical bar F edges. The crystal structure of HfF4 center dot 3H(2)O, previously determined by the photo method, is refined. The refined data on the geometric characteristics of the coordination polyhedron of the Hf atom and the system of hydrogen bonds in the structure are obtained.
引用
收藏
页码：541 / 546
页数：6
相关论文
共 50 条
  • [41] Crystal structure of form B monoclinic crystal of insulin
    Ding, JH
    Wan, ZL
    Chang, WR
    Liang, DC
    [J]. PROGRESS IN NATURAL SCIENCE, 1997, 7 (06) : 729 - 735
  • [42] Optimization of the structure and morphology of monoclinic phase nanoscale zirconium dioxide
    Wu, Song
    Liu, Shikai
    Chen, Yingxin
    Wang, Jialin
    Han, Bibo
    Liu, Chaofan
    Zhu, Zhiyuan
    Shen, Shaoyi
    Yu, Zhigang
    Zhang, Zhaobo
    Zheng, Xinhua
    [J]. MRS COMMUNICATIONS, 2024, 14 (04) : 646 - 652
  • [43] CRYSTAL STRUCTURE OF A TRIMERIC FORM OF TECHNETIUM OXIDE TETRAFLUORIDE
    EDWARDS, AJ
    JONES, GR
    SILLS, RJC
    [J]. CHEMICAL COMMUNICATIONS, 1968, (19) : 1177 - &
  • [44] THE CRYSTAL AND MOLECULAR STRUCTURES OF BIS(ETHYLCYCLOPENTADIENYL) DICHLORIDE OF TITANIUM, ZIRCONIUM AND HAFNIUM
    董贻诚
    吴伸
    张荣光
    陈寿山
    [J]. Science Bulletin, 1983, (10) : 1343 - 1348
  • [45] Research status and progress in single crystal growth of zirconium, hafnium and their alloys
    Peng, Jiaqing
    Yin, Yanxi
    Wang, Xin
    Li, Jingshe
    Wang, Lijun
    [J]. Xiyou Jinshu/Chinese Journal of Rare Metals, 2015, 39 (06): : 562 - 569
  • [46] Crystal structures of mixed zirconium(IV) and hafnium(IV) fluoroethylenediaminetetraacetate complexes
    Mistryukov, VE
    Sergeev, AV
    Mikhailov, YN
    Shchelokov, RN
    Chuklanova, ER
    [J]. ZHURNAL NEORGANICHESKOI KHIMII, 1995, 40 (10): : 1651 - 1654
  • [47] Crystal Growth and Photoluminescence Properties of Reactive CVD-Derived Monoclinic Hafnium Dioxide
    Lozanov, Victor V.
    Baklanova, Natalya I.
    Shayapov, Vladimir R.
    Berezin, Alexey S.
    [J]. CRYSTAL GROWTH & DESIGN, 2016, 16 (09) : 5283 - 5293
  • [48] VIBRATIONAL-SPECTRA AND STRUCTURE OF ZIRCONIUM AND HAFNIUM CYCLOPENTADIENYL HYDRIDES
    KLEMENKOVA, ZS
    LOKSHIN, BV
    STRUNKINA, LI
    MINACHEVA, MK
    [J]. RUSSIAN CHEMICAL BULLETIN, 1994, 43 (09) : 1516 - 1521
  • [49] SYNTHESIS AND STRUCTURE OF ARYL-IMIDO DERIVATIVES OF ZIRCONIUM AND HAFNIUM
    PROFILET, RD
    ZAMBRANO, CH
    FANWICK, PE
    ROTHWELL, IP
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 201 : 321 - INOR
  • [50] Electronic structure and lattice stability in the dihydrides of titanium, zirconium, and hafnium
    Kul'kova, SE
    Muryzhnikova, ON
    Naumov, II
    [J]. PHYSICS OF THE SOLID STATE, 1999, 41 (11) : 1763 - 1770
12345