Palladium-Catalyzed Three-Component Tandem Reaction for One-pot Highly Stereoselective Synthesis of (Z)-α-Hydroxymethyl Allylic Sulfones

被引：26

作者：

Hou, Yunlei ^{[1
]}

Shen, Qi ^{[1
]}

Li, Zefei ^{[1
]}

Chen, Shaowei ^{[1
]}

Zhao, Yanfang ^{[1
]}

Qin, Mingze ^{[1
]}

Gong, Ping ^{[1
]}

机构：

[1] Shenyang Pharmaceut Univ, Key Lab Struct Based Drug Design & Discovery, Minist Educ, Shenyang 110016, Liaoning, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2018年 / 360卷 / 04期

关键词：

allylic sulfones; three-component tandem reaction; Pd-catalyzed; sulfonyl hydrazides; allenes; C-H AMINATION; ARYL IODIDES; ALLENYLBORONATE PLATFORM; ORGANIC-SYNTHESIS; ALLYLATION; ALLENES; HYDRAZIDES; ALCOHOLS; AMINES; SULFONYLATION;

D O I：

10.1002/adsc.201701011

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A novel method is reported for the stereoselective synthesis of highly functionalized allyl aryl sulfones. This protocol is based on a Pd-catalyzed three-component tandem reaction of sulfonyl hydrazides and aryl iodides with allenes and exhibits high (Z)-selectivity, good yields, minimal waste, ample product scope, and operational simplicity.

引用

页码：631 / 636

页数：6

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