(Triphenyl phosphite)gold(I)-catalyzed intermolecular hydroamination of alkenes and 1,3-dienes

被引：91
|
作者：
Giner, Xavier
Najera, Carmen [1 ]
机构：
[1] Univ Alicante, Dept Quim Organ, E-03080 Alicante, Spain
来源：
ORGANIC LETTERS | 2008年 / 10卷 / 14期
关键词：
D O I：
10.1021/ol801104w
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Intermolecular addition of different sulfonamides to alkenes and conjugated dienes can be carried out using a low loading of (triphenyl phosphite)gold(I) chloride and silver triflate as a catalytic mixture. The reaction can be performed under conventional thermal or microwave conditions and at rt in the case of dienes. Terminal alkenes undergo regioselective hydroamination at the internal carbon atom and dienes at the less substituted double bond.
引用
收藏
页码：2919 / 2922
页数：4
相关论文
共 50 条
  • [41] Cobalt(I)-catalyzed 1,4-hydrovinylation reactions of 1,3-dienes with functionalized terminal alkenes under mild conditions
    Hilt, G
    Lüers, S
    SYNTHESIS-STUTTGART, 2002, (05): : 609 - 618
  • [42] PSiP-Pincer Type Palladium-Catalyzed Dehydrogenative Borylation of Alkenes and 1,3-Dienes
    Kirai, Naohiro
    Iguchi, Shoichiro
    Ito, Tatsuyoshi
    Takaya, Jun
    Iwasawa, Nobuharu
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2013, 86 (07) : 784 - 799
  • [43] Organogermanium Analogues of Alkenes, Alkynes, 1,3-Dienes, Allenes, and Vinylidenes
    Lee, Vladimir Ya.
    MOLECULES, 2023, 28 (04):
  • [44] Oxidative cyclization of nitriles with alkenes or 1,3-dienes on nickel(0)
    Ohashi, Masato
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
  • [45] REGIOSELECTIVITY IN THE META PHOTOCYCLOADDITION OF SUBSTITUTED BENZENES TO ALKENES AND 1,3-DIENES
    VANDERHART, JA
    MULDER, JJC
    CORNELISSE, J
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1991, 61 (01) : 3 - 13
  • [46] Homogenous Pd catalysis for enantioselective intermolecular hydrofunctionalizations of 1,3-dienes
    Adamson, Nathan
    Malcolmson, Steven
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
  • [47] Gold-catalyzed isomerization of unactivated allenes into 1,3-dienes under ambient conditions
    Ting, Chun-Ming
    Hsu, Yi-Ling
    Liu, Rai-Shung
    CHEMICAL COMMUNICATIONS, 2012, 48 (52) : 6577 - 6579
  • [48] Gold(I)-catalyzed intra- and intermolecular hydroamination of unactivated olefins
    Zhang, JL
    Yang, CG
    He, C
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (06) : 1798 - 1799
  • [49] Rare earth metal catalyzed intermolecular hydroamination of alkenes
    Hultzsch, Kai
    Soltys, John
    Schickhofer, Lisa
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257
  • [50] Gold(I)-catalyzed intra- and intermolecular hydroamination of unactivated olefins
    Zhang, Junliang
    Yang, Cai-Guang
    He, Chuan
    Journal of the American Chemical Society, 2006, 128 (06): : 1798 - 1799
12345