Electrochemical Oxidation of Reactive Blue 222 on Boron-Doped Diamond Electrodes

被引：0
|
作者：
Rangel, Manuel [1 ]
Nava, Jose L. [1 ]
Peralta-Hernandez, Juan M. [2 ]
Carreno, Gilberto [1 ]
Guerra-Sanchez, Ricardo J. [2 ]
机构：
[1] Univ Guanajuato, Dept Ingn Geomat & Hidraul, Guanajuato 36000, Mexico
[2] Ctr Innovac Aplicada Tecnol Competitivas CIATEC, Dept Invest Ambiental, Guanajuato 37545, Mexico
来源：
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE | 2013年 / 8卷 / 03期
关键词：
Degradation of organics; Boron-doped diamond electrode; Reactive blue 222; Electrochemical oxidation; WASTE-WATER; MASS-TRANSPORT; COAGULATION; ELECTROCOAGULATION; MINERALIZATION; ACID;
D O I：
暂无
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Electrochemical oxidation of reactive blue 222 (1.6 mM, 1300 mg dm(-3) COD) in 0.5 M Na2SO4 aqueous media (which resembles a textile wastewater) on a boron-doped diamond electrode (BDD) was studied, using bulk electrolysis. The influence of current density and hydrodynamics was investigated. The degradation rate depends on current density and with hydrodynamics. Generated carboxylic acids such as ascorbic, oxalic, benzoic, citric, fumaric and maleic were detected and quantified by HPLC measures. The electrolysis with a BDD electrode at 20 mA cm(-2) and mean linear flow velocity of 146 cm s(-1)was the only experiment that led to 100% mineralization of reactive blue 222, with an energy consumption of 11.8 KWh m(-3) and fractional integral current efficiency of 0.7.
引用
收藏
页码：3310 / 3320
页数：11
相关论文
共 50 条
  • [41] Electrochemical oxidation of phenol on boron-doped diamond electrode
    Kornienko, G. V.
    Chaenko, N. V.
    Maksimov, N. G.
    Kornienko, V. L.
    Varnin, V. P.
    [J]. RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2011, 47 (02) : 225 - 229
  • [42] Electrochemical oxidation of phenol at boron-doped diamond electrode
    Iniesta, J
    Michaud, PA
    Panizza, M
    Cerisola, G
    Aldaz, A
    Comninellis, C
    [J]. ELECTROCHIMICA ACTA, 2001, 46 (23) : 3573 - 3578
  • [43] Pt-implanted boron-doped diamond electrodes for electrochemical oxidation of hydrogen peroxide
    Ivandini, TA
    Sato, R
    Makide, Y
    Fujishima, A
    Einaga, Y
    [J]. CHEMISTRY LETTERS, 2004, 33 (10) : 1330 - 1331
  • [44] Electrochemical oxidation of boron-doped diamond electrodes for the treatment of chemical nickel plating baths
    Rheindorf, Angela
    Sen, Seema
    Bund, Andreas
    [J]. Galvanotechnik, 2019, 110 (08): : 1440 - 1444
  • [45] Electrochemical treatment of wastewater containing phenolic compounds: oxidation at boron-doped diamond electrodes
    A.M. Polcaro
    A. Vacca
    S. Palmas
    M. Mascia
    [J]. Journal of Applied Electrochemistry, 2003, 33 : 885 - 892
  • [46] Recent developments and advances in boron-doped diamond electrodes for electrochemical oxidation of organic pollutants
    He, Yapeng
    Lin, Haibo
    Guo, Zhongcheng
    Zhang, Wenli
    Li, Hongdong
    Huang, Weimin
    [J]. SEPARATION AND PURIFICATION TECHNOLOGY, 2019, 212 : 802 - 821
  • [47] Electrochemical oxidation of underivatized-nucleic acids at highly boron-doped diamond electrodes
    Ivandini, TA
    Sarada, BV
    Rao, TN
    Fujishima, A
    [J]. ANALYST, 2003, 128 (07) : 924 - 929
  • [48] The electrochemical oxidation of homocysteine at boron-doped diamond electrodes with application to HPLC amperometric detection
    Chailapakul, O
    Siangproh, W
    Sarada, BV
    Terashima, C
    Rao, TN
    Tryk, DA
    Fujishima, A
    [J]. ANALYST, 2002, 127 (09) : 1164 - 1168
  • [49] Influence of Supporting Electrolyte on the Electrochemical Oxidation of Formic Acid on Boron-Doped Diamond Electrodes
    Fierro, Stephane
    Honda, Yuki
    Einaga, Yasuaki
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2013, 86 (06) : 749 - 754
  • [50] Mechanistic aspects of the sonoelectrochemical degradation of the reactive dye Procion Blue at boron-doped diamond electrodes
    Foord, JS
    Holt, KB
    Compton, RG
    Marken, F
    Kim, DH
    [J]. DIAMOND AND RELATED MATERIALS, 2001, 10 (3-7) : 662 - 666
12345