Molecular packing based on a π-stacked screw via self-assembly

被引：10
|
作者：
Liu, ZH [1 ]
He, C [1 ]
Duan, CY [1 ]
You, XZ [1 ]
机构：
[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Nanjing, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 1999年 / 2卷 / 07期
基金：
中国国家自然科学基金;
关键词：
platinum complex; pi-pi stacking; rigid molecular tweezers; supramolecular aggregate;
D O I：
10.1016/S1387-7003(99)00068-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new platinum(II) complex, C24H16N10S2Pt .3H2O, bis(4,5-diazafluorene-9-one thiosemicarbazato) platinum(II) trihydrate, has been synthesized. Crystals of it are trigonal, space group P3(2) with cell parameters of a = 10.696(4), c = 19.748(6) Angstrom and Z = 3. The ligands are coordinated to the platinum(II) atom by two imino nitrogen atoms N(3) and N(8), and two sulfur atoms S(1) and S(2) forming a rigid molecular tweezers maintained by intramolecular pi-pi stacking. Detailed crystal structure analyses exhibit that the one-dimensional 3(2) screw robust supramolecular aggregate was achieved by intermolecular pi-pi stacking interaction between the extensive delocalization rr-system ligands via self-assembly and the aggregates were linked by hydrogen bonding. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：279 / 282
页数：4
相关论文
共 50 条
  • [41] Multiply reconfigurable 'plug and play' molecular logic via self-assembly
    de Silva, A. Prasanna
    Dobbin, Catherine M.
    Vancea, Thomas P.
    Wannalerse, Boontana
    CHEMICAL COMMUNICATIONS, 2009, (11) : 1386 - 1388
  • [42] Regulating self-assembly and molecular recognition via mechanical forces.
    Baneyx, G
    Krammer, A
    Craig, D
    Schulten, K
    Vogel, V
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 220 : U266 - U267
  • [43] Conducting polymer/metal oxide nanocomposite via molecular self-assembly
    Liu, YC
    Wu, CG
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 214 : 254 - INOR
  • [44] Molecular assembly and self-assembly: Molecular nanoscience for future technologies
    de Wild, M
    Berner, S
    Suzuki, H
    Ramoino, L
    Baratoff, A
    Jung, TA
    CHIMIA, 2002, 56 (10) : 500 - 505
  • [45] Molecular assembly and self-assembly - Molecular nanoscience for future technologies
    De Wild, M
    Berner, S
    Suzuki, H
    Ramoino, L
    Baratoff, A
    Jung, TA
    MOLECULAR ELECTRONICS III, 2003, 1006 : 291 - 305
  • [46] Relationship Between Molecular Structure, Single crystal Packing and Self-Assembly Behavior: A Case Based on Pyrene Imide Derivatives
    Li, Xiaojun
    Zhang, Shilong
    Chen, Wangqiao
    Han, Hongjing
    Qiu, Meizhen
    Chen, Jiawen
    Zhang, Qichun
    CHEMISTRY-A EUROPEAN JOURNAL, 2022, 28 (03)
  • [47] Machine learning prediction of self-assembly and analysis of molecular structure dependence on the critical packing parameter
    Ishiwatari, Yuuki
    Yokoyama, Takahiro
    Kojima, Tomoya
    Banno, Taisuke
    Arai, Noriyoshi
    MOLECULAR SYSTEMS DESIGN & ENGINEERING, 2024, 9 (01) : 20 - 28
  • [48] Self-assembly, molecular packing, and electron transport in n-type polymer semiconductor nanobelts
    Briseno, Alejandro L.
    Mannsfeld, Stefan C. B.
    Shamberger, Patrick J.
    Ohuchi, Fumio S.
    Bao, Zhenan
    Jenekhe, Samson A.
    Xia, Younan
    CHEMISTRY OF MATERIALS, 2008, 20 (14) : 4712 - 4719
  • [49] Understanding Self-Assembly and Molecular Packing in Methylcellulose Aqueous Solutions Using Multiscale Modeling and Simulations
    Wu, Zijie
    Collins, Audrey M.
    Jayaraman, Arthi
    BIOMACROMOLECULES, 2024, 25 (03) : 1682 - 1695
  • [50] Photophysical, electrochemical, self-assembly, and molecular packing properties of a sulfur-decorated perylene derivative
    Ma, Yongshan
    Zhang, Fengxia
    Jiang, Tianyi
    Ren, Huixue
    Wei, Xiaofeng
    Zhu, Yanyan
    Huang, Xianqiang
    CANADIAN JOURNAL OF CHEMISTRY, 2019, 97 (11) : 780 - 787
12345