Electrical properties of mixtures of fatty acid methyl esters from different vegetable oils

被引:27
|
作者
Corach, J. [1 ]
Sorichetti, P. A. [2 ]
Romano, S. D. [1 ,3 ]
机构
[1] Univ Buenos Aires, Fac Ingn, GER, RA-1063 Buenos Aires, DF, Argentina
[2] Univ Buenos Aires, Fac Ingn, Lab Sistemas Liquidos, RA-1063 Buenos Aires, DF, Argentina
[3] Consejo Nacl Invest Cient & Tecn, RA-1033 Buenos Aires, DF, Argentina
关键词
Fatty Acid Methyl Ester (FAME); Conductivity; Permittivity; Characterization; BIODIESEL;
D O I
10.1016/j.ijhydene.2011.12.089
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The dependence on temperature of the permittivity and conductivity of mixtures of Fatty Acid Methyl Esters (FAME) was determined between 300 K and 343 K, in the frequency range from 20 Hz to 2 MHz. Samples were made from oil of sunflower, corn, grape, chia, canola, jatropha, coconut and cottonseed. Permittivity fits very well to a linear function of temperature, the fitting parameters falling within a narrow range for all samples. Conductivity follows an Arrhenius dependence with activation energies between 0.202 eV and 0.252 eV. The results show that measurements of electrical properties, successfully used for the characterization of FAME from soybean oil, as reported in previous works, can also be employed in FAME obtained from different feedstocks. This generalization is relevant for laboratory and industrial characterization and quality control, and also for the application of "on line" measurements in automated production systems. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:14735 / 14739
页数:5
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