Controlled Radical Copolymerization of Naturally-Occurring Terpenes with Acrylic Monomers in Fluorinated Alcohol

被引：0

作者：

Matsuda, Masaru ^{[1
]}

Satoh, Kotaro ^{[1
]}

Kamigaito, Masami ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Chikusa Ku, Nagoya, Aichi 4648603, Japan

来源：

KGK-KAUTSCHUK GUMMI KUNSTSTOFFE | 2013年 / 66卷 / 05期

关键词：

Radical copolymerization; Terpene; Fluoroalcohol; Acrylic monomer; RAFT polymerization; BETA-PINENE; POLYMERS; LIMONENE; BIOMASS;

D O I：

暂无

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Naturally-occurring terpenes, such as d-limonene and beta -pinene, were copolymerized with electron-withdrawing polar vinyl monomers including methyl acrylate (MA) or methyl methacrylate (MMA). Fluorinated alcohols as the solvents enhanced the copolymerizability to produce copolymers with moderate incorporation of the terpenes up to 34 mol% for the copolymerization with MA. The thermal properties of the obtained copolymer improved as the incorporation of terpenes increased, in which the glass transition temperature of the MA-based copolymers reached around 80 degrees C. Furthermore, the controlled/living radical copolymerizations of the terpenes with MA were investigated with a trithiocarbonate as the RAFT agent.

引用

页码：51 / 56

页数：6

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