Tropolone as a High-Performance Robust Anchoring Group for Dye-Sensitized Solar Cells

被引：103

作者：

Higashino, Tomohiro ^{[1
]}

Fujimori, Yamato ^{[1
]}

Sugiura, Kenichi ^{[1
]}

Tsuji, Yukihiro ^{[1
]}

Ito, Seigo ^{[2
]}

Imahori, Hiroshi ^{[1
,3
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Mol Engn, Nishikyo Ku, Kyoto 6158510, Japan

[2] Univ Hyogo, Grad Sch Engn, Himeji, Hyogo 6712280, Japan

[3] Kyoto Univ, Inst Integrated Cell Mat Sci WPI iCeMS, Nishikyo Ku, Kyoto 6158510, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 31期

关键词：

anchoring groups; light harvesting; porphyrinoids; sensitizers; solar cells; 12 PERCENT EFFICIENCY; ORGANIC-DYES; PORPHYRIN SENSITIZERS; RUTHENIUM SENSITIZERS; CRYSTAL-STRUCTURE; COMPLEXES; TIO2; METALLOMESOGENS; EXCHANGE; DESIGN;

D O I：

10.1002/anie.201502951

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A tropolone group has been employed for the first time as an anchoring group for dye-sensitized solar cells (DSSCs). The DSSC based on a porphyrin, YD2-o-C8T, with a tropolone moiety exhibited a power-conversion efficiency of 7.7%, which is only slightly lower than that observed for a reference porphyrin, YD2-o-C8, with a conventional carboxylic group. More importantly, YD2-o-C8T was found to be superior to YD2-o-C8 with respect to DSSC durability and binding ability to TiO2. These results unambiguously demonstrate that tropolone is a highly promising dye-anchoring group for DSSCs in terms of device durability as well as photovoltaic performance.

引用

页码：9052 / 9056

页数：5

共 50 条

[21] Zinc Porphyrins with a Pyridine-Ring-Anchoring Group for Dye-Sensitized Solar Cells
Lu, Jianfeng
Xu, Xiaobao
Li, Zhihong
Cao, Kun
Cui, Jin
Zhang, Yibo
Shen, Yan
Li, Yi
Zhu, Jun
Dai, Songyuan
Chen, Wei
Cheng, Yibing
Wang, Mingkui
CHEMISTRY-AN ASIAN JOURNAL, 2013, 8 (05) : 956 - 962
[22] The Carbazole Compounds Endowed with Phosphonic Anchoring Group for Sensitizer in Dye-Sensitized Solar Cells
Kusumawati, Y.
Pamungkas, B. S.
2ND INTERNATIONAL CONFERENCE ON CHEMISTRY AND MATERIAL SCIENCE (IC2MS), 2020, 833
[23] A novel pyridinium hemicyanine dye with carboxylate anchoring group and its application in dye-sensitized solar cells
Shan, Yifan
Tang, Jie
Lai, Hua
Tan, Hongwei
Yang, Fan
Fang, Qiang
Audebert, Pierre
Pron, Adam
TETRAHEDRON LETTERS, 2012, 53 (11) : 1341 - 1344
[24] Design Enhancements for High Performance Dye-Sensitized Solar Cells
Parmar, K.
Kianimanesh, A.
Freiheit, T.
Park, S. S.
JOURNAL OF SOLAR ENERGY ENGINEERING-TRANSACTIONS OF THE ASME, 2013, 135 (03):
[25] High performance organic photosensitizers for dye-sensitized solar cells
Im, Hunbae
Kim, Sukwon
Park, Chanmoo
Jang, Seok-Hoon
Kim, Chang-Ju
Kim, Kyungkon
Park, Nam-Gyu
Kim, Chulhee
CHEMICAL COMMUNICATIONS, 2010, 46 (08) : 1335 - 1337
[26] High-Performance Molybdenum Diselenide Electrodes Used in Dye-Sensitized Solar Cells and Supercapacitors
Jia, Jinbiao
Wu, Jihuai
Dong, Jia
Tu, Yongguang
Lan, Zhang
Fan, Leqing
Wei, Yuelin
IEEE JOURNAL OF PHOTOVOLTAICS, 2016, 6 (05): : 1196 - 1202
[27] Engineering of the electron donor of triarylamine sensitizers for high-performance dye-sensitized solar cells
Xia, Qi
Liang, Mao
Tan, Yulin
Gao, Weixue
Ouyang, Liyan
Ge, Gaoyang
Sun, Zhe
Xue, Song
ORGANIC ELECTRONICS, 2015, 17 : 285 - 294
[28] Metal-Free Tetrathienoacene Sensitizers for High-Performance Dye-Sensitized Solar Cells
Zhou, Nanjia
Prabakaran, Kumaresan
Lee, Byunghong
Chang, Sheng Hsiung
Harutyunyan, Boris
Guo, Peijun
Butler, Melanie R.
Timalsina, Arnod
Bedzyk, Michael J.
Ratner, Mark A.
Vegiraju, Sureshraju
Yau, Shuehlin
Wu, Chun-Guey
Chang, Robert P. H.
Facchetti, Antonio
Chen, Ming-Chou
Marks, Tobin J.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (13) : 4414 - 4423
[29] Tuning the Energy Level of Organic Sensitizers for High-Performance Dye-Sensitized Solar Cells
Xu, Mingfei
Wenger, Sophie
Bala, Hari
Shi, Dong
Li, Renzhi
Zhou, Yanzhou
Zakeeruddin, Shaik M.
Graetzel, Michael
Wang, Peng
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (07): : 2966 - 2973
[30] Design of high-performance dye-sensitized solar cells by variation of the dihedral angles of dyes
Kim, Kwang-Myeong
Hong, Jong-In
TETRAHEDRON, 2016, 72 (51) : 8387 - 8392

← 1 2 3 4 5 →