Crystal structure of Nb5Si3-xP0.5+x (x=0-0.5)

被引:2
|
作者
Lomnytska, YF
Oryshchyn, SV
Kuz'ma, YB
Guérin, R
机构
[1] Franko Natl Univ, UA-79005 Lvov, Ukraine
[2] Univ Rennes 1, CNRS, Chim Solide & Inorgan Mol Lab, UMR 6511, F-35042 Rennes, France
关键词
Reflection; Crystal Structure; Inorganic Chemistry; Structure Type; Ternary Compound;
D O I
10.1007/s10789-005-0262-2
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The structure of the ternary compound Nb5Si3-xP0.5+x (x = 0-0.5) is determined by single-crystal x-ray diffraction: sp: gr. P6(3)mc, a = 1.32350(5) nm, c = 0.52954(1) nm; R-F 0.028, R-w = 0.081 for 547 reflections with F-hkl > 4.0 sigma(F-hkl). Relations between the structure of Nb5Si3-xP5+x the Mn5Si3 structure type, and its derivatives are discussed.
引用
收藏
页码:1067 / 1072
页数:6
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