Preparation and characterization of La0.9Sr0.1Ga0.8Mg0.2O3-δ thin film deposited by radio frequency magnetic sputtering

被引:3
|
作者
Yang Jianjun [1 ,2 ]
Ma Wenhui [1 ,2 ]
Yu Jie [1 ,3 ]
Chen Xiuhua [4 ]
Xing Jie [1 ,4 ]
Li Rui [1 ,4 ]
机构
[1] Natl Engn Lab Vacuum Met, Kunming 650093, Peoples R China
[2] Kunming Univ Sci & Technol, Fac Met & Energy Engn, Kunming 650093, Peoples R China
[3] Kunming Univ Sci & Technol, Fac Environm Sci & Engn, Kunming 650093, Peoples R China
[4] Yunnan Univ, Fac Phys Sci & Technol, Kunming 650091, Peoples R China
关键词
solid state reaction; magnetic sputtering; annealing; island growth; rare earths; PREFERRED ORIENTATION; FUEL-CELL; OXIDE; DESORPTION; ADSORPTION; ELECTROLYTE; GROWTH; CARBON; SOFC;
D O I
10.1016/S1002-0721(12)60324-X
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
La0.9Sr0.1Ga0.8Mg0.2O3-delta (LSGM) electrolyte materials were synthesized by the solid state reaction method. The conductivity of LSGM materials was detected by four probe method, and it was 0.08 S/cm at 850 degrees C. Dense and uniform films of LSGM materials were deposited by the magnetic sputtering on substrates of Si and La0.7Sr0.3Cr0.5Mn0.5O3-delta (LSCM). The experimental results showed that the deposition rates dropped and the average grain sizes of the films enlarged with increase in the substrate temperatures. In the sputtering process, the LSGM film was deposited with preferred growth direction. After annealing, the preferred growth direction disappeared and the film surface became smoother and denser. Through observing the deposition process, deposition mechanism was proposed, which was consistent with a model of island growth.
引用
收藏
页码:582 / 588
页数:7
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