1,4-asymmetric induction in the Nozaki-Hiyama reaction

被引：17

作者：

Maguire, RJ ^{[1
]}

Mulzer, J ^{[1
]}

Bats, JW ^{[1
]}

机构：

[1] UNIV FRANKFURT,INST ORGAN CHEM,D-60439 FRANKFURT,GERMANY

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 31期

关键词：

D O I：

10.1016/0040-4039(96)01161-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of allyl bromides 3a-c bearing a stereogenic carbon substituent at C-2 are synthesised in four steps from methyl acrylate. These are found to react with aldehydes, mediated by chromium(ll) chloride, to furnish syn-4-alkoxyalkan-1-ols 4 in good to excellent diastereoselectivity. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：5487 / 5490

页数：4

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