1,4-asymmetric induction in the Nozaki-Hiyama reaction

被引：17
|
作者：
Maguire, RJ [1 ]
Mulzer, J [1 ]
Bats, JW [1 ]
机构：
[1] UNIV FRANKFURT,INST ORGAN CHEM,D-60439 FRANKFURT,GERMANY
来源：
TETRAHEDRON LETTERS | 1996年 / 37卷 / 31期
关键词：
D O I：
10.1016/0040-4039(96)01161-6
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of allyl bromides 3a-c bearing a stereogenic carbon substituent at C-2 are synthesised in four steps from methyl acrylate. These are found to react with aldehydes, mediated by chromium(ll) chloride, to furnish syn-4-alkoxyalkan-1-ols 4 in good to excellent diastereoselectivity. Copyright (C) 1996 Elsevier Science Ltd
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收藏
页码：5487 / 5490
页数：4
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