Synthesis and properties of carbon-carbon composite material based on nanoporous carbon

被引:0
|
作者
Sokolov, V. V. [1 ]
Kukushkina, Yu. A. [1 ]
Tomkovich, M. V. [1 ]
机构
[1] Russian Acad Sci, Ioffe Phys Tech Inst, St Petersburg 194021, Russia
关键词
Carbide; Compaction Pressure; Nanoporous Carbon; Thermochemical Treatment; Porous Structure Parameter;
D O I
10.1134/S1070427215060154
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Effect of synthesis parameters of carbon-carbon nanoporous composites in the form of compact bodies with various geometric shapes on their structure and properties was studied. The synthesis process includes three technological stages: molding of blanks with prescribed size and shape powdered Ti, Si, B, Mo, etc. carbides, their thermal treatment with methane to give a carbide-pyrocarbon composite, thermochemical treatment of the composite with chlorine to give the final material, carbon-carbon nanoporous composite in which nanoporous carbon is a filler, and pyrocarbon, a binder. It is shown that the ratio between the carbide phases and pyrocarbon, compaction pressure, and temperature of chlorination of the chemical composition of carbide affect the properties of the composite. The carbon-carbon composites synthesized contain nanopores 0.7-3 nm in size and micropores and have a large specific surface area (up to 1000 m(2) g(-1)). The volume of the nanopores in the composites varies within the range 0.42-0.79 cm(3) g(-1).
引用
收藏
页码:990 / 998
页数:9
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