Selective Hydrogenation of 5-Hydroxymethylfurfural into 2,5-Bis(hydroxymethyl)furan over a Cheap Carbon-Nanosheets-Supported Zr/Ca Bimetallic Catalyst

被引：33
|
作者：
Zhang, Junhua [1 ]
Qi, Zhaohua [1 ]
Liu, Yao [1 ]
Wei, Junnan [2 ]
Tang, Xing [2 ]
He, Liang [1 ]
Peng, Lincai [1 ]
机构：
[1] Kunming Univ Sci & Technol, Fac Chem Engn, BiomassChem Grp, Kunming 650500, Yunnan, Peoples R China
[2] Xiamen Univ, Coll Energy, Xiamen 361005, Fujian, Peoples R China
来源：
ENERGY & FUELS | 2020年 / 34卷 / 07期
基金：
中国国家自然科学基金;
关键词：
CROSS-LINKED POLYMER; REDUCTIVE ETHERIFICATION; BIOMASS; 2,5-DIHYDROXYMETHYLFURAN; CONVERSION;
D O I：
10.1021/acs.energyfuels.0c01128
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
Catalytic transfer hydrogenation (CTH) of 5-hydroxymethylfurfural (HMF) into 2,5-bis(hydroxymethypfuran (BHMF) is an important method for the catalytic upgrading of biomass-derived platform compounds to fuels and chemicals, and the development of effective and economical catalysts for this purpose is of great significance. In this work, we designed and prepared a new carbon-nanosheets (CNS)-supported Zr/Ca bimetallic catalyst (ZrCa@CNS) with low cost by a "gel-blowing" strategy. Comprehensive studies revealed that ZrCa(2)@CNS-600 exhibited good catalytic activity on the CTH of HMF into BHMF via Meerwein-Ponndorf-Verley (MPV) reduction, and an 84.2% BHMF yield with a 91.2% HMF conversion was obtained in isopropyl alcohol at 190 degrees C in 10 h. ZrCa(2)@CNS-600 exhibited good heterogeneity, reusability, and stability, and it is readily recovered from the reaction mixture by filtration and consecutively recycled/reused for six times without an obvious loss in its catalytic activity.
引用
收藏
页码：8432 / 8439
页数：8
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