Hydrogen-bond networks of 1,3-imidazolidine-2-thione: synthesis and structures of complexes of silver(I), copper(I), cadmium(II) and zinc(II)

被引：8

作者：

Zhu, Qinlei ^{[1
]}

Chu, Wei ^{[1
]}

Huang, Rudan ^{[1
]}

Zhang, Jing ^{[1
]}

Xu, Yanqing ^{[1
]}

机构：

[1] Beijing Inst Technol, Sch Sci, Dept Chem, Beijing 100081, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2008年 / 61卷 / 21期

关键词：

1,3-Imidazolidine-2-thione; Hydrogen-bond networks; Structure;

D O I：

10.1080/00958970802051041

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Solution reactions of silver(I), copper(I), cadmium(II) and zinc(II) salts with 1,3-imidazolidine-2-thione (imdt) under diverse conditions yielded four complexes: [Cd(SC3H6N2)(2)(Ac)(2)] (1), [Zn(SC3H6N2)(2)(Ac)(2)] (2), [Cu-2(SC3H6N2)(6)]SO4 (3) and [Ag-2(SC3H6N2)(6)]SO4 (4). Complexes 1 and 2 are 1D and 2D hydrogen-bond aggregations. Complexes 3 and 4 are isostructural 3D hydrogen-bond networks. The diverse coordination modes of imdt and different anions are the major factors for three distinct hydrogen-bond structures.

引用

页码：3390 / 3400

页数：11

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